Scientific American Supplement, No. 586, March 26, 1887Various
Science
Scientific American Supplement, No. 586, March 26, 1887
Various
Science -- Periodicals
A rod of impure copper, containing arsenic, iron, zinc, and other
impurities, was next substituted, using hydrochloric acid as a solvent in
place of sulphuric acid. In the course of a day the copper had entirely
dissolved and precipitated itself on the negative electrode, the impurities
remaining in solution. The copper, after having been washed, dried, and
weighed, gave identical results with regard to percentage with a careful
gravimetric estimation. I have lately used this method, and obtained
excellent results with respect to the analysis of commercial copper,
especially in the estimation of small quantities of arsenic, thus enabling
the experimenter to perform his investigation on a much larger quantity
than when precipitation is resorted to, at the same time avoiding the
precipitated copper carrying down with it the arsenic. I have in this
manner detected arsenic in commercial copper when all other methods have
totally failed. I have also found the above method especially applicable
with respect to the analysis of brass.
With respect to ammoniacal dissolution, which I will briefly mention, a rod
composed of an alloy of copper and silver was experimented upon, the copper
becoming entirely dissolved and precipitating itself on the platinum
electrode, the whole of the silver remaining suspended to the positive
electrode in an aborescent form. Arsenide of zinc was similarly treated,
the arsenic becoming precipitated in like manner on the platinum electrode.
Various other alloys, being experimented upon, gave similar results.
I may also, in the last instance, mention that I have found the above
methods of electro-dissolution peculiarly adapted for the preparation of
unstable compounds such as stannic nitrate, potassic ferrate, ferric
acetate, which are decomposed on the application of heat, and in some
instances have succeeded by the following means of crystallizing the
resulting compound obtained.--_Chem. News_.
* * * * *
A NEWLY DISCOVERED SUBSTANCE IN URINE.
Dr. Leo's researches on sugar in urine are interesting, and tend to correct
the commonly accepted views on the subject. Professor Scheibler, a chemist
well known for his researches on sugar, has observed that the determination
of the quantity of that substance contained in a liquid gives different
results, according as it is done by Trommer's method or with the
polariscope. As sugar nowadays is exclusively dealt with according to the
degree of polarization, this fact is of enormous value in trade. Scheibler
has isolated a substance that is more powerful in that respect than grape
sugar. Dr. Leo's researches yield analogous results, though in a different
field. He has examined a great quantity of diabetic urine after three
different methods, namely, Trommer's (alkaline solution of copper); by
fermentation; and with the polarization apparatus. In many cases the
results agreed, while in others there was a considerable difference.
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