Scientific American Supplement, No. 586, March 26, 1887Various
Science
Scientific American Supplement, No. 586, March 26, 1887
Various
Science -- Periodicals
The precipitated salt, after slight washing, is dissolved in water and
strong solution ammonia added. A clean iron plate is immersed in the
solution to remove any trace of copper. This plate must be cleaned
occasionally so as to remove any reduced copper, which will impede its
action. As soon as the liquid is free from copper, it is left alkaline and
well stirred so as to facilitate peroxidation and removal of iron, which
forms a film on the bath. When this ceases, the liquid is rendered neutral
by addition of sulphuric acid, and filtered or decanted. The solution, when
properly diluted, has sp. gr. about 1.06 at 60° F. It is best to work the
bath with a weak current for a short time until the liquid yields a fine
white deposit. Too strong a current must be avoided.
If the copper has not been removed, it will deposit on the anodes when the
bath is at rest. It should then be removed by scouring.
Copper produces a reddish tinge, which is by no means unpleasant compared
with the dazzling whiteness of the nickel deposit. If this is desired, it
is far better to use a separate bath, using anodes of suitable composition.
The want of adhesion between the deposited coating and the article need not
be feared if cleanliness be attended to and the article, while in the bath,
be not touched by the hands.
The bath should be neutral, or nearly so, slightly acid rather than
alkaline. It is obvious that, as such a liquid has no detergent action on a
soiled surface, scrupulous care must be taken in scouring and rinsing.
Boiling alkaline solutions and a free use of powdered pumice and the
scrubbing brush must on no account be neglected.
A few words on the construction of the tanks. A stout wood box, which need
not be water-tight, is lined with sheet lead, the joints being blown, _not
soldered_. An inner casing of wood which projects a few inches above the
lead lining is necessary in order to avoid any chance of "short circuiting"
or damage to the lead from the accidental falling of anodes or any article
which might cut the lead. It is by no means a necessity that the lining
should be such as to prevent the liquid getting to the lead.
On a future occasion I hope to supplement this paper with the analysis of
the double sulphates used, and an account of the behavior of
electrolytically prepared crucibles and dishes as compared with those now
in the market.--_Chem. News_.
* * * * *
CHILLED CAST IRON.
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