Scientific American Supplement, No. 595, May 28, 1887Various
Science
Scientific American Supplement, No. 595, May 28, 1887
Various
Science -- Periodicals
By the study of thin sections I have, during several years, been
endeavoring to trace the minute structure of some of these substances. In
no class of materials is it more necessary to guard one's self against
errors of observation arising from changes induced in the substance
during the operations which are necessary to the preparation of
transparent sections of hard substances. Unfortunately, too, it is the
custom of the natives to prepare the substance for the market by an
imperfect calcination, and hitherto I have only been able to study
specimens procured in the markets which have been subjected to this
process. It is obviously desirable, before attempting to interpret the
structures exhibited, under the microscope, to compare the fresh and
uncalcined materials with those that have been more or less altered by
heat.
Tabasheer would seem, from Brewster's experiments, to be a very intimate
admixture of two and a half parts of air with one part of colloidal
silica. The interspaces filled with air appear, at all events, in most
cases, to be so minute that they cannot be detected by the highest powers
of the microscope which I have been able to employ. It is this intimate
admixture of a solid with a gas which probably gives rise to the curious
and anomalous properties exhibited by this singular substance.
The ultra-microscopical vesicles filled with air in all probability give
rise to the opalescence which is so marked a property of the substance.
Their size is such as to scatter and throw back the rays at the blue end
of the spectrum and to transmit those at the red end.
When the vesicles of the substance are filled with Canada balsam, and a
thin slice is cut from it, this opalescence comes out in the most
striking manner. Very thin sections are of a rich orange yellow by
transmitted light, and a delicate blue tint by reflected light. I do not
know of any substance which in such thin films displays such striking
opalescence.
That the excessively low refractive power of tabasheer is connected with
the mechanical admixture of the colloidal silica with air seems to be
proved by the experiments of Brewster, showing that with increase of
density there was an increase in the refractive index from 1.111 in
specimens of the lowest specific gravity to 1.182 in those of the highest
specific gravity. Where the surface was hard and dense, Brewster found
the refractive index to approach that of semi opal. The wonderful thing
is that a substance so full of cavities containing gas should
nevertheless be transparent.
By the kindness of Mr. F. Rutley, F.G.S., I am able to supply a drawing
taken from one of my sections of tabasheer.
The accompanying woodcut gives some idea of the interesting structures
exhibited in some sections of tabasheer, though much of the delicacy and
fidelity of the original drawing has been lost in transferring it to the
wood.
Public-domain text, read in full here on John Shaqi.
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