Scientific American Supplement, No. 611, September 17, 1887Various
Science
Scientific American Supplement, No. 611, September 17, 1887
Various
Science -- Periodicals
The agitator in which the kerosene distillate is treated commonly
takes a charge of 465 barrels. To this quantity of distillate two
carboys of oil of vitriol is added, and the oil and acid are agitated
together for 20 minutes. The tarry acid having been allowed to settle
is drawn off, and seven carboys more of acid is added. Agitation
having been effected for 30 or 40 minutes, the tarry acid is removed
as before. Another similar treatment with seven carboys of acid
follows, and occasionally a fourth addition of acid is made. The oil
is next allowed to remain at rest for an hour, any acid which settles
out being drawn off, and cold (or, in winter, slightly warmed) water
is allowed to pass down through the oil in fine streams, this
treatment being continued, without agitation of the oil, for half an
hour, or until the dark color which the oil assumed on treatment with
acid is removed. The water is then drawn off, 10 barrels of solution
of caustic soda (sp. gr. 15 deg. B.) is added, and agitation conducted for
15 minutes. The caustic soda solution having been drawn off, 30
barrels of a solution of litharge in caustic soda is added. This
solution is made by dissolving caustic soda in water to a density of
18 deg. B. and then adding the litharge. Agitation with this solution is
continued for about six hours, or until the oil is thoroughly
deodorized. About 100 lb. of sublimed sulphur is then added, and the
agitation is continued for another two hours. The oil having been
allowed to settle all night, the litharge solution is drawn off, and
the oil run into a shallow tank or "bleacher," where it is exposed to
the light to improve its color, and is, if necessary, steamed to drive
off the lighter hydrocarbons and raise the flashing point to the legal
minimum of 95 deg. F. To raise the flashing point from 73 deg. F. to 95 deg. F.
(Abel test) is stated to involve in practice a loss of 10 per cent.,
the burning quality of the oil being at the same time seriously
impaired, and upon this ground the Ontario refiners in 1886 petitioned
for a reduction of the test standard.
The average percentage yield of the various products is given in the
following table:
Naphtha. 5
Kerosene. 42
Gas oil. 8
Tar. 25
Coke. 10
Loss (including water). 10
---
100
There are a dozen petroleum refineries in Canada, and the annual
outturn of kerosene is about 200,000 barrels of 45 imperial gallons
per annum. The total consumption of kerosene in Canada is about
300,000 barrels, one-third of which is manufactured in the United
States. The United States oil is subject to a duty of 40 cents on the
package and 7-1/5 cents per imperial gallon on the contents, besides
which there is an inspection fee of 30 cents per package. Of
lubricating oils the outturn is from 75,000 to 100,000 barrels per
annum.
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