Scientific American Supplement, No. 620, November 19,1887Various
Science
Scientific American Supplement, No. 620, November 19,1887
Various
Science -- Periodicals
Although the hydrogen and oxygen present in pure cellulose are in the
same relative proportions as in water, they do not exist as water in
the compound. There is, however, in cotton a certain amount of water
present in a state of loose combination with the cellulose, and the
celluloid bodies previously referred to appear to contain water
similarly combined, but in greater proportion. Oxycellulose is another
body present in the cotton fiber. It is a triple cellulose, in which
four atoms of hydrogen are replaced by one atom of oxygen, and like
cellulose forms nitro compounds analogous to nitro glycerine. It is
probable that the presence of this oxycellulose has a marked influence
upon the behavior of cotton, especially with dye matters. The earthy
substances in cotton are also of importance. These are potassium
carbonate, chloride, and sulphate, with similar sodium salts, and
these vary in different samples of cotton, and possibly influence its
properties to some extent. Then there are oily matters in the young
fiber which, upon its ripening, become the waxy matter which Dr.
Schunk has investigated. Resin also is present, and having a high
melting point is not removed by the manipulative processes that cotton
is subjected to. When this is in excessive amount, it comes to the
surface of the goods after dyeing.
* * * * *
SYNTHESIS OF STYROLENE.
MM. Vabet and Vienne, in a recent number of _Comptes Rendus_, state
that by passing a current of acetylene through 200 grammes of benzene
containing 50 grammes of aluminum chloride for 30 hours the oily
liquid remaining after removal of the unaltered aluminum chloride by
washing was found to yield, on fractional distillation, three distinct
products. The first, which came over between 143 deg. and 145 deg., and which
amounted to 80 per cent. of the whole, consisted of pure cinnamene or
styrolene (C_{6}H_{5}.CH.CH_{2}), which is one of the principal
constituents of liquid storax, and was synthetized by M. Berthelot by
passing acetylene and benzene vapor through a tube heated to redness.
The second fraction, coming over at 265 deg.-270 deg., consisted of diphenyl
ethane ((C_{6}H_{5})_{2} CH.CH_{3}); and the third fraction, boiling
at 280 deg.-286 deg., was found to consist entirely of dibenzyl
(C_{6}H_{5}.CH_{2}.CH_{2}.C_{6}H_{5}), a solid substance isomeric with
diphenyl ethane. These syntheses afford another instance of the
singular action of aluminum chloride in attacking the benzene nucleus.
* * * * *
NOTES ON SACCHARIN.
By EDWARD D. GRAVILL, F.C.S., F.R.M.S.
Now that a supply of this reputed substitute for sugar has been placed
upon the London market, it will doubtless have attracted the attention
of many pharmacists, and as information having reference to its
characters and properties is as yet somewhat scarce, the following
notes may be of interest.
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