Scientific American Supplement, No. 620, November 19,1887Various
Science
Scientific American Supplement, No. 620, November 19,1887
Various
Science -- Periodicals
The compound, like most of the organic acids, shows a characteristic
reaction with ferro and ferrid cyanide of potassium. In the former
case no change is perceptible until boiled when a greenish white
turbidity appears, with the liberation of small quantities of
hydrocyanic acid. In the latter case a trace also of this acid is set
free, with the formation of a very distinct green solution, the latter
reaction being very perceptible with a few drops of a 1 in 1,000
solution of saccharin in water. Heated with lime, very distinct odors
of benzoic aldehyde are developed.
Saccharin possesses very decided acid properties, and combines readily
with alkalies or alkaline carbonates, forming anhydro-ortho
sulphamine-benzoates of the same, in the latter case at the expense of
the carbonic anhydride, causing strong effervescence. These
combinations are very soluble in water, the alkaline carbonate thus
forming a ready medium for the solution of this acid, which alone is
so sparingly soluble. Another advantage of some importance is that,
while the harshness of flavor perceptible in a simple solution of the
acid is destroyed, the great sweetness appears to be distinctly
intensified and refined.
The following shows the solubility of saccharin in the various liquids
quoted, all, with the exception of the boiling water, being taken at
60 deg. F.:
Boiling water 0.60 parts per 100 by volume.
Cold water 0.20 " " "
Alcohol 0.800 4.25 " " "
Rectified spirit 0.838 3.20 " " "
Ether 0.717 1.00 " " "
Chloroform 1.49 0.20 " " "
Benzene 0.40 " " "
Petroleum ether insoluble.
It is also sparingly soluble in glycerin and fixed oils, and to a
greater or less extent in volatile oils. Benzoic aldehyde dissolves
saccharin in large quantities.
I was somewhat disappointed at the slight solubility of saccharin in
ether, as it has been repeatedly stated to be very soluble in that
liquid.
The quantity of saccharin required to communicate an agreeable degree
of sweetness, like sugar, differs with the material to be sweetened;
but from half to one and half grains, according to taste, will be
found sufficient for an ordinary breakfast cup full of tea or coffee
infusion.--_Pharm. Jour._
* * * * *
ALCOHOL AND TURPENTINE.
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