Scientific American Supplement, No. 643, April 28, 1888Various
Science
Scientific American Supplement, No. 643, April 28, 1888
Various
Science -- Periodicals
As this mixture of substances naturally suggested the composition of
the "mother liquors" from salt brines, Mr. Price made an analysis of
such a sample of "bittern" from the Snow Hill furnace, Kanawha Co.,
W.Va., obtaining the following composition:
In 1000 c.c. In 200 c.c.
Grammes. Grains.
Calcium chlorideš 299.70 925.8
Magnesium " 56.93 175.7
Strontium " 1.47 4.5
Sodium " 20.16 62.2
Potassium " 5.13 15.8
------ ------
383.39 1184.0
šTrace of bromide.
There is of course some variation in the bittern obtained from
different brines, but it appears of interest to call attention to this
correspondence in composition, as indicating that the liquid for
filling such grenades is obtained by adding two volumes of water to
one of the "bittern." The latter statement is fairly proved by the
presence of the bromine, and certainly from an economical standpoint
such should be its method of manufacture.--_Amer. Chem. Jour._
* * * * *
MOLECULAR WEIGHTS.
A new and most valuable method of determining the molecular weights of
non-volatile as well as volatile substances has just been brought into
prominence by Prof. Victor Meyer (_Berichte_, 1888, No. 3). The method
itself was discovered by M. Raoult, and finally perfected by him in
1886, but up to the present has been but little utilized by chemists.
It will be remembered that Prof. Meyer has recently discovered two
isomeric series of derivatives of benzil, differing only in the
position of the various groups in space. If each couple of isomers
possess the same molecular weight, a certain modification of the new
Van't Hoff-Wislicenus theory as to the position of atoms in space is
rendered necessary; but if the two are polymers, one having a
molecular weight n times that of the other, then the theory in its
present form will still hold. Hence it was imperative to determine
without doubt the molecular weight of some two typical isomers. But
the compounds in question are not volatile, so that vapor density
determinations were out of the question. In this difficulty Prof.
Meyer has tested the discovery of M. Raoult upon a number of compounds
of known molecular weights, and found it perfectly reliable and easy
of application. The method depends upon the lowering of the
solidifying point of a solvent, such as water, benzine, or glacial
acetic acid, by the introduction of a given weight of the substance
whose molecular weight is to be determined. The amount by which the
solidifying point is lowered is connected with the molecular weight,
M, by the following extremely simple formula: M = T x (P / C); where C
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