Scientific American Supplement, No. 717, September 28, 1889Various
Science
Scientific American Supplement, No. 717, September 28, 1889
Various
Science -- Periodicals
Sulphur chloride gives a perfectly white product with the fresh oil,
but, when oxidized, the product is very dark, almost black. The iodine
absorption of the fresh oil thus obtained is very high, but falls
rapidly by oxidation or blowing. A curious fact has been disclosed
with reference to the oxidation of this and similar oils. If such an
oil be mixed with lard oil, olive oil, or sperm oil, it thickens by
oxidation, but is perfectly soluble. Such a mixture is largely used in
weaving or spinning. Commercial samples of linseed oil, when
cold-drawn, have a much higher iodine absorption, probably due to the
same cause. Oils extracted by CS2 are very much higher than the same
oils, especially if hot-pressed.--_Chem. News._
* * * * *
THE PYRO DEVELOPER WITH METABISULPHITE OF POTASH.
By Dr. J. M. EDER.
Lately I called attention to the metabisulphite of potassium as an
addition to the pyro solution for development, and can give now some
of my experiences with this salt.
The metabisulphite of potassium, which was introduced into the market
by Dr. Schuchardt, and whose correct analysis is not known yet, is a
white crystal, which in a solid condition, as well as in an aqueous
solution, has a strong smell of sulphurous acid. An aqueous 2 per
cent. solution of this salt dissolves pyrogallic acid to a weak
yellowish color, being distinguished from the more light brown
solution of sulphite of soda and pyro. The solution kept very well for
four weeks in half-filled bottles, and showed a better preservation
than the usual solution of pyro and sulphite of soda. More than 2 per
cent. of the metabisulphite of potassium is without any advantage. If
this solution is mixed with soda, a picture will develop rapidly, but
the same will show a strongly yellow coloration in the gelatine film.
Sulphite of soda has to be added to the soda solution to obtain an
agreeable brownish or black tone in the negatives.
If the contents of metabisulphite and pyro-soda developer are
increased, it will act very slowly; larger quantities of the
metabisulphite of potassium, therefore, act like a strong retarder. In
small quantities there is no injurious retarding action, but it will
have the effect that the plates obtain very clear shadows in this
developer, and that the picture appears slower, and will strengthen
more slowly. The strongly retarding action of larger quantities of
metabisulphite might be accounted for in that the bisulphite will
give, with the carbonate of soda, monosulphite and soda bicarbonate,
which latter is not a strong enough alkali to develop the bromide of
silver strongly with pyro. An increase of soda compensates this
retarding action of the metabisulphite of potassium.
Good results were obtained by me with this salt after several tests,
by producing the following solutions:
A.
Pyrogallic acid 4 grammes.
Metabisulphite of potassium 11/2 "
Water 100 c. c.
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