Scientific American Supplement, No. 794, March 21, 1891Various
Science
Scientific American Supplement, No. 794, March 21, 1891
Various
Science -- Periodicals
If the mixed oil so obtained, which we may call "phenoloid oil," is
cracked by itself, no very striking result is obtained, the 40
percent. of paraffin present cracking in the usual way, and yielding a
certain amount of illuminants, but if this oil be cracked in the
presence of carbon, and be made to pass over and through a body of
carbon heated to a dull red heat, then it is converted largely into
benzene, the most valuable of the illuminants, and also being the one
to which coal gas owes the largest proportion of its illuminating
power, it is manifestly the right one to use in order to enrich it.
On cracking the phenoloid oil, the paraffins yield ethane, propane,
and marsh gas, etc., in the usual way, while the phenol interacts with
the carbon to form benzene--
Phenol. Benzene.
C6H5HO + C = C6H6 + CO.
And in the same way the cresol first breaks down to toluene in the
presence of the carbon, and this in turn is broken down by the heat to
benzene.
A great advantage of this oil is that the flashing point is 110, and
so is well above the limit, thus doing away with the dangers and
troubles inseparable from the storage of light naphtha in bulk.
In using this oil as an enricher, it must be cracked in the presence
of carbon, and it is of the greatest importance that the temperature
should not be too high, as the benzene is easily broken down to
simpler hydrocarbons of far lower illuminating value. This fact is
very clearly brought out by a series of experiments I have made, in
which the phenoloid oil was cracked by passing it through an iron tube
packed with coke and heated to various temperatures, the hydrocarbons
being much more easily broken up under these conditions than if mixed
with diluents, such as water gas:
RESULTS OBTAINED ON CRACKING PHENOLOID OIL.
I. II. III.
Temperature. 600 deg. C. 800 deg. C. 1,000 deg. C.
Volume of gas per gallon. 41.6 c.f. 76.8 c.f. 121.6 c.f.
COMPOSITION OF THE GAS.
Hydrogen. 34.0 36.0 37.0
Methane. 20.0 26.0 49.0
Olefines. 11.0 5.0 Nil.
Ethane. 16.0 9.0 Nil.
Carbon monoxide. 13.0 15.0 12.0
Carbon dioxide. 2.0 4.0 2.0
Oxygen. 2.0 1.0 Nil.
Nitrogen. 2.0 4.0 Nil.
This analysis shows that if the temperature is allowed to reach a
cherry red, complete decomposition of the illuminating hydrocarbons is
taking place, and a gas of practically no illuminating value results.
The power of regulating the temperature and the body of carbon as a
cracking medium in the Van Steenbergh water gas plant especially fits
it for using this oil, and removes the objections which could have
been urged against the lighter naphthas.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account