Scientific American Supplement, No. 794, March 21, 1891Various
Science
Scientific American Supplement, No. 794, March 21, 1891
Various
Science -- Periodicals
The tube thus contained chlorine saturated with bromine vapor. The
silent discharge on being passed through this tube did not produce any
different effect than for chlorine alone. So we may conclude that
bromine vapor also does not undergo any allotropic condensation when
subjected to the influence of a silent discharge of electricity. The
fact that oxygen gas is capable of undergoing condensation while
chlorine and bromine are not is easily explained. The oxygen atom,
being divalent, is capable of uniting itself to two other atoms of
oxygen or other elements, and thus with oxygen forming ozone. The
atoms of chlorine and bromine, however, being only monovalent, have
all their affinity satisfied when they are united to a single other
atom of chlorine and bromine. It is not possible, therefore, that
condensation can take place if the atoms remain monovalent. Hydrogen
gas and iodine vapor are in a similar manner debarred from undergoing
condensation. Mr. Vernon, therefore, comes to the conclusion that it
is most improbable that any other element but oxygen will be found
capable of undergoing molecular condensation when in the gaseous state
and subjected to the silent discharge.
* * * * *
ESTIMATING CARBON IN ORGANIC SUBSTANCES.
BY J. MESSINGER.
This is an improvement on the author's method of two years ago. The
method is now applicable to compounds with which previously low
results were obtained.
The substance is weighed into a small tube 24 mm. long and 11 mm.
wide, and is then introduced into the decomposition flask, which
contains 6 to 8 grms. of chromic acid, care being taken that the
chromic acid does not come into contact with the substance under
analysis. The decomposition flask is fitted with a thistle funnel, and
is connected to the reversed condenser and apparatus shown in the
figure. Fifty c.c. of concentrated sulphuric acid are run into the
flask. During the whole of the operation a gentle current of air (free
from carbon dioxide) is passed through the apparatus. The asbestos
plate underneath the flask is then warmed, and thus the flask and
contents are warmed by radiant heat from the plate alone until the
sulphuric acid darkens. At this point, where decomposition of the
organic substance begins, the flame is entirely removed. The carbon
dioxide (with some carbon monoxide) passes through the condenser and
then over a heated mixture of copper oxide and lead chromate contained
in a tube 15 cm. long. The gas (CO2) then passes through a U-tube,
in one limb of which is sulphuric acid, in the other glacial
phosphoric acid.
[Illustration: APPARATUS FOR THE ESTIMATION OF CARBON IN ORGANIC
SUBSTANCES.]
Public-domain text, read in full here on John Shaqi.
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