Scientific American Supplement, No. 795, March 28, 1891Various
History
Scientific American Supplement, No. 795, March 28, 1891
Various
Science -- Periodicals
This meaning that, in immediate contact with the cold body, the
temperature is so reduced that the flame cannot exist, and so is
extinguished over a small area; while over a still larger space the
temperature is so reduced that it is not hot enough to bring about
decomposition of the heavy hydrocarbons with liberation of carbon to
the same extent as in hotter portions of the flame. Now, inasmuch as
when water is heated or boiled in an open vessel, the temperature
cannot rise above 100°C., and as the temperature of an ordinary flame
is over 1,000°C., it is evident that the burning gas can never be in
contact with the bottom of the vessel, or, in other words, the gas is
put out before combustion is completed, and the unburned gas and
products of incomplete combustion find their way into the air and
render it perfectly unfit for respiration.
The portion of the flame which is supposed to be the hottest is about
half an inch above the tip of the inner zone of the flame, and it is
at this point that most vessels containing water to be heated are made
to impinge on the flame; and it is this portion of the flame, also,
which is utilized for raising various solids to a temperature at which
they radiate heat.
In order to gain an insight into the amount of contamination which the
air undergoes when a geyser or cooking stove is at work, I have
determined the composition of the products of combustion, and the
unburned gases escaping when a vessel containing water at the ordinary
temperatures is heated up to the boiling point by a gas flame, the
vessel being placed, in the first case, half an inch above the inner
cone of the flame, and in the second, at the extreme outer tip of the
flame.
GASES ESCAPING DURING CHECKED COMBUSTION.
| Bunsen flame. | Luminous flame.
+-----------+-----------+-------------+----------
| Inner. | Outer. | Inner. | Outer.
+-----------+-----------+-------------+----------
Nitrogen | 75.75 | 79.17 | 77.52 | 69.41
Water vapor | 13.47 | 14.29 | 11.80 | 19.24
Carbon dioxide | 2.99 | 5.13 | 4.93 | 8.38
Carbon monoxide | 3.69 | Nil. | 2.45 | 2.58
Marsh gas | 0.51 | 0.31 | 0.95 | 0.39
Acetylene | 0.04 | Nil. | 0.27 | Nil.
Hydrogen | 3.55 | 0.47 | 2.08 | Nil.
+-----------+-----------+-------------+----------
| 100.00 | 100.00 | 100.00 | 100.00
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