Scientific American Supplement, No. 821, September 26, 1891Various
Science
Scientific American Supplement, No. 821, September 26, 1891
Various
Science -- Periodicals
The hygrometric nature of a gum or dextrin is a point of considerable
importance when the material is to be used for adhesive purposes. The
apparatus which we finally adopted after many trials for testing this
property consists simply of a tinplate box about 1 ft. square, with two
holes of 2 in. diameter bored in opposite sides. Through these holes is
passed a piece of wide glass tubing 18 in. long. This is fitted with
India rubber corks at each end, one single and the other double bored.
Through the double bored cork goes a glass tube to a Woulffe's bottle
containing warm water. A thermometer is passed into the interior of the
tube by the second hole. The other stopper is connected by glass tubing
to a pump, and thus draws warm air laden with moisture through the tube.
Papers gummed with the gums or dextrins, etc., to be tested are placed
in the tube and the warm moist air passed over them for varying periods,
and their proneness to become sticky noted from time to time. By this
means the gums can be classified in the order in which they succumbed to
the combined influences of heat and moisture. We find that in resisting
such influences any natural gum is better than a dextrin or a gum
substitute containing dextrin or gelatin. The Ghattis are especially
good in withstanding climatic changes.
Dextrins containing much starch are less hygroscopic than those which
are nearly free from it, as the same conditions which promote the
complete conversion of the starch into dextrin also favor the production
of sugars, and it is to these sugars probably that commercial dextrin
owes its hygroscopic nature. We have been in part able to confirm these
results by a series of tests of the same gums in India, but have not yet
obtained information as to their behavior in the early part of the year.
The fermentation of natural gum solutions is accompanied by a decrease
in the viscosity of the liquid and the separation of a portion of the
gum in lumps. Apparently those gums which contain most sugar, as
indicated by their reduction of Fehling's solution, are the most
susceptible to this change. Oxalic acid is formed by the fermentation,
which by combination with the lime present renders the fermenting liquid
turbid, and also some volatile acid, probably acetic.
We have made some experiments with a gum which readily fermented--in a
week--as to the respective value of various antiseptics in retarding the
fermentation. Portions of the gum solutions were mixed with small
quantities of menthol, thymol, salol, and saccharin in alkaline
solution, also with boric acid, sodium phosphate, and potash alum in
aqueous solution. Within a week a growth appeared in a portion to which
no antiseptic had been added; the others remained clear. After over five
months the solutions were again examined, when the following results
were observed:
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