Scientific American Supplement No. 822, October 3, 1891Various
Science
Scientific American Supplement No. 822, October 3, 1891
Various
Science -- Periodicals
or as preferred by some: H-O-H, is not in conformity with established
facts. Expressed as here shown, both hydrogen atoms are assigned equal
values, when in fact only _one of the atoms is united to oxygen in
form of hydroxyl_, while the second is loosely attached to the
univalent hydroxyl group. Viewed in this light, water then is
decomposed according to the equation: H_{2}O = H + (OH), never in this
manner: H_{2}O = 2H + O. Hence, water must be considered as a
combination of one hydrogen atom with one molecule of hydroxyl,
expressed by the formula H(OH), and it is this atom of hydrogen _not_
united to oxygen which is eliminated in the generation of oxygen or
substituted by metals and alkyl groups. The hydrogen in the hydroxyl
group cannot be substituted, excepting it be the entire group as such;
this is proved by the action of the halogens, in their phosphorus
compounds, upon water, when the halogen takes the place of the
hydroxyl group, but never that of the hydrogen.
Now as to some logical deductions from the foregoing considerations.
Hydrogen is by many looked upon as a true metal. This theory cannot be
directly proved by the above, but it is certainly greatly strengthened
thereby. To compare. Hydrogen is a powerful reducing agent; it is
similarly affected by the halogens, the hydroxyl group, the acid
radicals, oxygen and sulphur; hydrogen and members of the univalent
alkali metals group are readily interchangeable; it forms superoxides
analogous to the metals; its analogy to the alkali metals as exhibited
in the following:
H H(OH) HCl HNO_{3} H_{2}SO_{4} H_{2}S H_{2}O_{2}
K K(OH) KCl KNO_{3} Na_{2}SO_{4} Na_{2}S K_{2}O
But if we consider hydrogen as a gasiform metal, we naturally arrive
at the conclusion that _water is the hydroxide of this gasiform
metal_, that is _hydrogen hydroxide_, while gaseous hydrochloric and
hydrosulphuric acids would be looked upon as respectively the chloride
and the sulphide of the metal hydrogen. This would then lead to
curious conclusions concerning the hydroxyl group. This group would,
by this theory, become an oxygenated metal radical similar to the
hypothetical bismuthyl and uranyl, and yet one in which the metallic
character has disappeared as completely as in the ferrocyanic group.
An entirely new light is shed by this view upon the composition of
hydrogen peroxide, which would be looked at as two free hydroxyl
groups joined together thus: (OH)--(OH), analogous to our di-ethyl,
diphenyl, dicyanogen, etc. Considered as dihydroxyl, it would explain
the instability of this compound.
Public-domain text, read in full here on John Shaqi.
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