Scientific American Supplement No. 822, October 3, 1891Various
Science
Scientific American Supplement No. 822, October 3, 1891
Various
Science -- Periodicals
The ethers proper would also be placed in a new light by this new
conception of the constitution of the water molecule. The hydrogen in
the hydroxyl group, as is known, may be substituted by an alkyl group.
For instance, an alkyl may be substituted for the hydroxyl hydrogen in
an alcohol molecule, when an ether results. According to the new
theory this ether will no longer be considered as two alkyl groups
connected by an oxygen atom, but as a compound built up on the type of
water by the union of an alkyl group and an alkoxyl group. Thus
ethylic ether would not be represented by
C_{2}H_{5}
> O,
C_{2}H_{5}
as heretofore, but by the formula C_{2}H_{5}(OC_{2}H_{5}), which is
ethyl-ethoxol. Acetone would admit of a similar explanation.
Finally the assumption of dissimilarity in character of the hydrogen
atoms in the water molecule possibly may lead to the discovery of a
number of unlocked for isomerides.
Thus, by appropriate methods, it ought to become possible to introduce
the alkyl groups solely into the hydroxyl group (instead of into the
place of the loosely attached H-atom). In that case chemists might
arrive at an isomeride of methyl alcohol of the formula H.(OCH_{3}),
or at methoxyl hydride, a compound not alcoholic in character, or at a
nitroxyl hydride, H(ONO_{2}), not of an acidic nature. Oxychlorides
would be classed with this latter category, that is, they would be
looked on as water in which the free hydrogen atom has been
substituted by the metal, and the hydrogen atom of the hydroxyl by
chlorine. This example, indeed, furnishes a most characteristic
illustration of our theory. In the case just now assumed we arrive at
the oxychloride; when, however, the metal and chlorine change places
in the water molecule, the isomeric hypochlorous salts are the result.
It is true that such cases of isomerism are as yet unknown, but we do
know that certain metals, in our present state of knowledge, yield
oxychlorides only, while others only form hypochlorous salts. This
condition also explains why hypochlorites still possesses the
bleaching power of chlorine, while the same is not true of
oxychlorides. However, it seems needless to multiply examples in
further illustration of the theory.
* * * * *
THE FORMATION OF STARCH IN LEAVES.
In 1750, Bonnet, a Genevese naturalist, remarked that leaves immersed
in water became covered in the sun with small bubbles of a gas that he
compared to small pearls. In 1772, Priestley, after discovering that
the sojourn of animals in a confined atmosphere renders it
irrespirable, investigated the influence of plants placed in the same
conditions, and he relates, in these words, the discovery that he made
on the subject:
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