Scientific American Supplement No. 822, October 3, 1891Various
Science
Scientific American Supplement No. 822, October 3, 1891
Various
Science -- Periodicals
transparent liquid on filtration through paper, the volume is made up
directly with water to the 100 c.c. mark on the flask. Most sugar
solutions, however, will require the addition of a clarifying or
decolorizing agent in order to render them sufficiently clear and
colorless to polarize. In such case, before making up to the mark, a
saturated solution of subacetate of lead is added.
The quantity of this agent required will vary according to the quality
of the sugar; for sugar which has been grained in the strike pan and
washed in the centrifugals, from 3 to 15 drops will be required; for
sugar grained in the strike pan but not well washed in the
centrifugals, that is, sugar intended for refining purposes, from 15
to 30 drops will be required; for sugar not grained in the strike pan,
that is, "wagon" or "string sugar," "second sugar," etc., from 1 to 3
c.c. will be required. After adding the solution of subacetate of lead
the flask must be gently shaken, so as to mix it with the sugar
solution. If the proper amount has been added, the precipitate will
usually subside rapidly, but if not, the operator may judge of the
completeness of the precipitation by holding the flask above the level
of the eye and allowing an additional drop of subacetate of lead to
flow down the side of the flask into the solution; if this drop leaves
a clear track along the glass through the solution it indicates that
the precipitation is complete; if, on the other hand, all traces of
the drop are lost on entering the solution, it indicates that an
additional small quantity of the subacetate of lead is required. The
operator must learn by experience the point where the addition should
cease; a decided excess of subacetate of lead solution should never be
used.
The use of subacetate of lead should, in all cases, be followed by the
addition of "alumina cream" (aluminic hydrate suspended in water)[2]
in about double the volume of the subacetate solution used, for the
purpose of completing the clarification, precipitating excess of lead,
and facilitating filtration. In many cases of high grade sugars,
especially beet sugars, the use of alumina alone will be sufficient
for clarification without the previous addition of subacetate of lead.
[Footnote 2: Prepared as follows: Shake up powdered commercial
alum with water at ordinary temperature until a saturated
solution is obtained. Set aside a little of the solution, and to
the residue add ammonia, little by little, stirring between
additions, until the mixture is alkaline to litmus paper. Then
drop in additions of the portion left aside, until the mixture
is just acid to litmus paper. By this procedure a cream of
aluminum hydroxide is obtained suspended in a solution of
ammonium sulphate, the presence of which is not at all
detrimental for sugar work when added after subacetate of lead,
the ammonium sulphate precipitating whatever excess of lead may
be present.]
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