Scientific American Supplement, No. 841, February 13, 1892Various
Science
Scientific American Supplement, No. 841, February 13, 1892
Various
Science -- Periodicals
IV. Ordinary pressure:
10 grms. of cellulose, with 500 c.c. caustic
soda solution of sp. gr. 1.162 21.88
10 grms. of soft wood 35.45
10 " hard " 46.43
V. Pressure of five atmospheres:
10 grms. of cellulose, with 500 c.c. caustic
soda solution of sp. gr. 1.162 77.33
10 grms. of soft wood 97.13
10 " hard " 91.48
VI. Ordinary pressure:
10 grms. of cellulose, with 500 c.c. caustic
soda solution of sp. gr. 1.043 12.07
10 grms. of soft wood 28.37
10 " hard " 30.25
VII. Pressure of five atmospheres:
10 grms. of cellulose, with 500 c.c. of caustic
soda solution of sp. gr. 1.043 15.36
10 grms. of soft wood 50.96
10 " hard " 55.66
VIII. Pressure of ten atmospheres:
10 grms. of cellulose, with 200 c.c. caustic
soda solution of sp. gr. 1.043 20.28
10 grms. of soft wood 70.31
10 " hard " 65.59
From this it is evident that by increasing the temperature and
pressure the solvent action of the alkali is increased, but the
strength of the lye exercises an influence which is even more marked.
Thus, at a pressure of five atmospheres, the loss of cellulose was
0.75 with a caustic lye containing 14 per cent. of NaHO, while it was
only 0.05 with a lye of 8 per cent. NaHO.
To further elucidate the action of the alkali under the conditions
given above, the author has estimated the amount of precipitate which
alcohol gives with the soda solutions, after boiling with the wood:
1. 2. 3.
Specific gravity of NaHO solutions 1.043 1.09 1.162
Soft wood, ordinary pressure 1.043 traces 4.8
" pressure of five atmospheres 1.043 2.0 26.8
" " ten " 1.043 1.7 --
Hard wood, ordinary pressure 11.10 27.40 30.80
" pressure of five atmospheres 1.10 25.70 15.8
" " ten " traces 5.20 15.8
The estimation of the precipitate, produced in the soda solutions
employed in the experiments cited above, gives:
Soft wood, ordinary pressure 1.31 traces 2.0
" pressure of five atmospheres 15.94 16.0 24.80
" " ten " 17.00 25.4 --
Hard wood, ordinary pressure 5.40 6 5.60
" pressure of five atmospheres 9.40 15.40 33.60
" " ten " 14.00 18.40 33.60
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account