Scientific American Supplement, No. 841, February 13, 1892Various
Science
Scientific American Supplement, No. 841, February 13, 1892
Various
Science -- Periodicals
Heated in contact with sulphureted hydrogen,
it forms sulphides of boron and phosphorus and hydriodic acid, without
liberation of iodine. Metallic magnesium when slightly warmed reacts
with it with incandescence. When thrown into vapor of mercury, boron
phospho-di-iodide instantly takes fire.
The second phospho-iodide of boron obtained by M. Moissan is
represented by the formula BPI. It is formed when sodium or magnesium
in a fine state of division is allowed to act upon a solution of the
di-iodide just described in carbon bisulphide; or when boron
phospho-di-iodide is heated to 160 deg. in a current of hydrogen. It is
obtained in the form of a bright red powder, somewhat hygroscopic. It
volatilizes _in vacuo_ without fusion at a temperature about 210 deg., and
the vapor condenses in the cooler portion of the tube in beautiful
orange colored crystals. When heated to low redness it decomposes into
free iodine and phosphide of boron, BP. Nitric acid reacts
energetically with it, but without incandescence, and a certain amount
of iodine is liberated. Sulphuric acid decomposes it upon warming,
without formation of sulphurous and boric acids and free iodine. By
the continued action of dry hydrogen upon the heated compound the
iodine and a portion of the phosphorus are removed, and a new phosphide
of boron, of the composition B_{5}P_{3}, is obtained.--_Nature_.
* * * * *
BORON SALTS.
A paper upon the sulphides of boron is communicated by M. Paul
Sabatier to the September number of the _Bulletin de la Societe
Chimique. Nature_ gives the following: Hitherto only one compound of
boron with sulphur has been known to us, the trisulphide, B_{2}S_{3},
and concerning even that our information has been of the most
incomplete description. Berzelius obtained this substance in an impure
form by heating boron in sulphur vapor, but the first practical mode
of its preparation in a state of tolerable purity was that employed by
Wohler and Deville. These chemists prepared it by allowing dry
sulphureted hydrogen gas to stream over amorphous boron heated to
redness. Subsequently a method of obtaining boron sulphide was
proposed by Fremy, according to which a mixture of boron trioxide,
soot, and oil is heated in a stream of the vapor of carbon bisulphide.
M. Sabatier finds that the best results are obtained by employing the
method of Wohler and Deville. The reaction between boron and
sulphureted hydrogen only commences at red heat, near the temperature
of the softening of glass. When, however, the tube containing the
boron becomes raised to the temperature, boron sulphide condenses in
the portion of the tube adjacent to the heated portion; at first it is
deposited in a state of fusion, and the globules on cooling present an
opaline aspect. Further along the tube it is slowly deposited in a
porcelain like form, while further still the sublimate of sulphide
takes the form of brilliant acicular crystals. The crystals consist of
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