Scientific American, Volume 22, No. 1, January 1, 1870: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and Manufactures.Various
Science
Scientific American, Volume 22, No. 1, January 1, 1870: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and Manufactures.
Various
Science -- Periodicals; Technology -- Periodicals
One patent, by a complicated process, effects a union of metallic zinc
and iron; this, granulated and ground fine, then mixed with red lead
and oil, makes the paint. It is said to be the best of all the patented
stuffs.
It is astonishing how many use oils derived from coal, peat, or resin,
and tars of the same.
There are about fifty patents for this object and with all of them
before their eyes, the British Society for the Advancement of Art still
hold the $5,000 reward for a pigment or covering which will perfectly
protect from rust and fouling. However they may puff their products for
selling, no one has the temerity to claim that they deserve the reward.
We think it would be difficult to find so many expedients ever before
adopted for the accomplishment of any one object. These are all English
patents, England having necessarily been obliged to use iron for vessels
from its cheapness as well as its consequent first introduction there.
In the United States no patents worth mentioning have been granted.
The first requisites for a pigment or coating for iron are, that it
should not contain any copper--the corrosive action of that metal on
iron being intense. Then if for work exposed to air it should form
such a coating as to be impervious to that gaseous fluid, and be
so constituted chemically as not to be oxidizable by it; if under
water--especially sea water--to be impermeable to moisture, so elastic
as not to crack, so insoluble as not to chloridize; to form a perfect,
apparently hard, coating: and yet wear just enough to keep off
incrustation, barnacles, or growth of grass. In fact, this slow wearing
away is the only preventive of fouling in iron vessels. Wooden bottoms
may be poisoned by solutions of copper--and that metal has no superior
for such uses, especially when it is combined in mixture with mineral
or resinous tars and spirits--these compounds, however, are not only
useless on iron bottoms, but also injurious. What then is _the_
substance: 1st. One of the oxides of lead (red lead). 2d. The purest
oxide of iron to be found. If properly made these articles can be
carried to no higher state of oxidation, and respectively, as to order
named, they have no superiors for body and durability. By preference,
1st, red lead, either out of or under water; 2d, Prince's oxide of iron
only, out of water. The color of these paints--the first red, the latter
brown, may be hidden by a coat of white or tinted color. If there were
to be had in combination as a white paint, an oxide of lead and an oxide
of zinc, it would be immensely superior to either, but that such has not
been produced is rather the fault of carelessness than of possibility.
Zinc protects iron with great effect, but it is too rapidly worn in the
effort to be of lasting value. Hence the great desideratum, the yet to
be, the coming pigment is a white oxide of lead or a combined white
oxide of lead and white oxide of zinc, without sulphates or chlorides.
Public-domain text, read in full here on John Shaqi.
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