Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
As has already been intimated, the values of the velocities both of
hydrogen and of air molecules given above were measured at a definite
temperature, 32 deg. of our Fahrenheit thermometer, the freezing point of
water; and this introduces a very important point bearing on our
subject, namely, that the molecular velocities vary very greatly with
the temperature. Indeed, according to our theory, this very molecular
motion constitutes that state or condition of matter which we call
temperature. A hot body is one whose molecules are moving comparatively
rapidly, and a cold body one in which they are moving comparatively
slowly. Without, however, entering into further details, which would
involve the whole mechanical theory of heat, let me call your attention
to a single consequence of the principle I have stated.
When we heat hydrogen, air, or any mass of gas, we simply increase the
velocity of its moving molecules. When we cool the gas, we simply lessen
the velocity of the same molecules. Take a current of air which enters a
room through a furnace. In passing it comes in contact with heated iron,
and, as we say, is heated. But, as we view the process, the molecules of
the air, while in contact with the hot iron, collide with the very
rapidly oscillating metallic molecules, and fly back as a billiard-ball
would under similar circumstances, with a greatly increased velocity,
and it is this more rapid motion which alone constitutes the higher
temperature.
Consider, next, what must be the effect on the surface. A moment's
reflection will show that the normal pressure exerted by the molecular
storm, always raging in the atmosphere, is due not only to the impact of
the molecules, but also to the reaction caused by their rebound. When
the molecules rebound, they are, as it were, driven away from the
surface in virtue of the inherent elasticity both of the surface and of
the molecules. Now, what takes place when one mass of matter is driven
away from another--when a cannon-ball is driven out of a gun, for
example? Why, the gun _kicks_! And so every surface from which molecules
rebound must _kick_; and, if the velocity is not changed by the
collision, one half of the pressure caused by the molecular bombardment
is due to the recoil. From a heated surface, as we have said, the
molecules rebound with an increased velocity, and hence the recoil must
be proportionally increased, determining a greater pressure against the
surface.
Public-domain text, read in full here on John Shaqi.
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