Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
The nauseous, smelling gas we call sulphide of hydrogen has a density
only a little greater than that of air, and its molecules must therefore
move with very nearly as great velocity as the average air
molecule--that is to say, about fourteen hundred and eighty feet a
second; and we might therefore expect that, on opening a jar of the gas,
its molecules would spread instantly through the surrounding atmosphere.
But, so far from this, if the air is quiet, so that the gas is not
transported by currents, a very considerable time will elapse before the
characteristic odor is perceived on the opposite side of an ordinary
room. The reason is obvious: the molecules must elbow their way through
the crowd of air molecules which already occupy the space, and can
therefore advance only slowly; and it is obvious that, the oftener they
come into collision with their neighbors, the slower their progress must
be. Knowing, then, the mean velocity of the molecular motion, and being
able to measure by appropriate means _the rate of diffusion_, as it is
called, we have the data from which we can calculate both the number of
collisions in a second and also the mean path between two successive
collisions. The results, as we must expect, are of the same order as the
other molecular magnitudes. But, inconceivably short as the free[C] path
of a molecule certainly is, it is still, in the case of hydrogen gas,
136 times the diameter of the moving body, which would certainly be
regarded among men as quite ample elbow-room.
[C] There is an obvious distinction between the free and the
disturbed path of a molecule, and we can not overlook in
our calculations the perturbations which the collisions
necessarily entail. Such considerations greatly complicate
the problem, which is far more difficult than would appear
from the superficial view of the subject that can alone be
given in a popular lecture.
Although, in this lecture, I have as yet had no occasion to mention the
radiometer, I have by no means forgotten my main subject, and everything
which has been said has had a direct bearing on the theory of this
remarkable instrument; and still, before you can understand the great
interest with which it is regarded, we must follow out another line of
thought, converging on the same point.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account