Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
While, however, it thus appears that the results of Graham's
investigation were in strict accordance with Dalton's theory, it must
also be evident that Graham was the first to observe the exact numerical
relation which obtains in this class of phenomena, and that
all-important circumstance entitles him to be regarded as the discoverer
of the law of diffusion. The law, however, at first enunciated, was
purely empirical, and Graham himself says that something more must be
assumed than that gases are vacua to each other, in order to explain all
the phenomena observed; and according to his original view this
representation of the process was only a convenient mode of expressing
the final result. Such has proved to be the case.
Like other great men, Graham built better than he knew. In the progress
of physical science during the last twenty-five years, two principles
have become more and more conspicuous, until at last they have
completely revolutionized the philosophy of chemistry. In the first
place, it has appeared that a host of chemical as well as of physical
facts are cooerdinated by the assumption that all substances in the state
of gas have the same molecular volume, or, in other words, contain the
same number of molecules in a given space; and in the second place, it
has become evident that the phenomena of heat are simply the
manifestations of molecular motion. According to this view, the
temperature of a body is the _vis viva_ of its molecules; and, since all
molecules at a given temperature have the same _vis viva_, it follows
that the molecules must move with velocities which are inversely
proportional to the square roots of the molecular weights. Moreover,
since the molecular volumes are equal, and the molecular weights
therefore proportional to the densities of the aeriform bodies in which
the molecules are the active units, it also follows that the velocities
of the molecules in any two gases are inversely proportional to the
square roots of their respective densities. Thus the simple numerical
relations first observed in the phenomena of diffusion are the direct
result of molecular motion; and it is now seen that Graham's empirical
law is included under the fundamental laws of motion. Thus Graham's
investigation has become the basis of the new science of molecular
mechanics, and his measurements of the rates of diffusion prove to be
the measures of molecular velocities.
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