Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
and used in his system for the indices of a plane the values
_h_:_k_:_l_, which are also in the ratio of whole numbers, and usually
of simpler whole numbers than _m_:_n_:_p_. This seems a small
difference; for _h_ _k_ _l_ in the last proportion are obviously the
reciprocals of _m_ _n_ _p_ in the first; but the difference, small as it
is, causes a wonderful simplification of the formulae which express the
relations between the parts of a crystal. From the last proportion we
derive at once
(1/_h_).(_a_/_A_) = (1/_k_).(_b_/_B_) = (1/_l_).(_c_/_C_),
which is the form in which Miller stated his fundamental law.
[G] For example, the native crystals
of sulphur have _a_:_b_:_c_ = 1:2.340:1.233.
Crystals of gypsum have _a_:_b_:_c_ = 1:0.413:0.691.
Crystals of tin-stone have _a_:_b_:_c_ = 1:1:0.6724.
And crystals of common salt have _a_:_b_:_c_ = 1:1:1.
If _P_ represents the "pole" of a face whose "indices" are _h_ _k_ _l_,
that is, represents the point where the radius drawn normal to the face
meets the surface of the sphere circumscribed around the crystal (the
sphere of projection, as it is called), and if _X_, _Y_, _Z_ represent
the points where the axes of the crystal meet the same spherical
surface,[H] then it is evident that _X Y_, _X Z_, and _Y Z_ are the
arcs of great circles, which measure the inclination of the axes to each
other, and that _P X_, _P Y_, and _P Z_ are arcs of other great circles,
which measure the inclination of the plane (_h_ _k_ _l_) on planes
normal to the respective axes; and, also, that these several arcs form
the sides of spherical triangles thus drawn on the sphere of projection.
Now, it is very easily shown that
(_a_/_h_).cos _P X_ = (_b_/_k_).cos _P Y_ = (_c_/_l_).cos _P Z_;
and by means of this theorem we are able to reduce a great many problems
of crystallography to the solution of spherical triangles.
[H] The origin of the axes is always taken as the center of the
sphere of projection.
Another very large class of problems in crystallography is based on the
relation of faces in a zone; that is, of faces which are all parallel
to one line called the zone axis, and whose mutual intersections,
therefore, are all parallel to each other. If, now, _h_ _k_ _l_ and
_p_ _q_ _r_ are the indices of any two planes of a zone (not parallel to
each other), any other plane in the same zone must fulfill the condition
expressed by the simple equation
u._u_ + v._v_ + w._w_ = _o_,
where _u_ _v_ and _w_ are the indices of the third plane, and u v w
have the values
u = _k_._r_ - _l_._q_
v = _l_._p_ - _h_._r_
w = _h_._q_ - _k_._p_.
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