The beautiful blue tint of the semi-transparent "white" of a boiled
plover's egg is due to a fine-particled cloud dispersed in the clear
albumen. London milk used to be "sky-blue" for a similar reason,
before the recent legislation against the adulteration of food. The
blue eyes of our fair-haired race and of young foxes are not due to
any "pigment"–that is to say, a separable self-coloured substance–but
to a fine cloud floating in a transparent medium which reflects blue
rays of light as blue smoke does. The iris of the eye can and often
does develop a pigment, but it is a brown one. When present in small
quantity it produces a green-coloured iris, the pale yellow-brown
being added to the blue cloud-caused colouring. When present in larger
quantity the same pigment gives us brown and so-called "black"
eyes. The blue colours in birds' feathers and insects' wings are
produced without blue pigment by special effects of reflection, and
where green is the colour it is often due to the addition of a small
quantity of yellow pigment to what would otherwise look blue: though
some caterpillars and grasshoppers have a real green pigment in their
skin. Flowers, on the other hand, have true soluble blue "pigments,"
and green ones too, notably that called leaf-green or chlorophyll.
The little green tree frog has no blue or green pigment in its skin;
only a yellow pigment. Sometimes rare specimens are found in which
the yellow pigment is absent altogether, and then the little frog is
turquoise-blue in colour. But there is no blue pigment in the skin;
only a finely-clouded translucent film overlying a dead-black deep
layer of the skin, and the result is that the frog is of a wonderful
pure blue. Sometimes the commoner large edible frog is found with a
similar absence of yellow pigment (I found some in a garden near Geneva
six years ago), and then all the parts of its skin which usually are
green show as brilliant blue.
It is at first difficult to believe that such fine, smoothly-spread
turquoise blue as that of the blue frog is due merely to a "reflection
effect," and that there is no blue pigment present which would show
as blue if light were transmitted through it, or could be separated
and dissolved in some medium. Yet this is undoubtedly the case. The
nearest experimental production of such a blue surface without blue
pigment is obtained by first varnishing a black board, and when the
varnish is nearly dry passing a sponge wetted with water over it.
Some of the varnish is precipitated from its solution in the spirit
(or it may be turpentine) as a fine cloud, and until the water has
evaporated it looks like blue paint, as the poet Goethe found when
cleaning a picture. It would be interesting to know more precisely the
precautions to be taken in order to get the blue colour in this way in
fullest degree.
Public-domain text, read in full here on John Shaqi.
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