Six Lectures on Light: Delivered In The United States In 1872-1873Tyndall, John
Science
Six Lectures on Light: Delivered In The United States In 1872-1873
Tyndall, John
Light
A large number of substances examined by Stokes, when excited by the
invisible ultra-violet waves, have been proved to emit light. You know
the rate of vibration corresponding to the extreme violet of the
spectrum; you are aware that to produce the impression of this colour,
the retina is struck 789 millions of millions of times in a second. At
this point, the retina ceases to be useful as an organ of vision; for,
though struck by waves of more rapid recurrence, they are incompetent
to awaken the sensation of light. But when such non-visual waves are
caused to impinge upon the molecules of certain substances--on those
of sulphate of quinine, for example--they compel those molecules, or
their constituent atoms, to vibrate; and the peculiarity is, that the
vibrations thus set up are _of slower period_ than those of the
exciting waves. By this lowering of the rate of vibration through the
intermediation of the sulphate of quinine, the invisible rays are
brought within the range of vision. We shall subsequently have
abundant opportunity for learning that transparency to the visible by
no means involves transparency to the invisible rays. Our bisulphide
of carbon, for example, which, employed in prisms, is so eminently
suitable for experiments on the visual rays, is by no means so
suitable for these ultra-violet rays. Flint glass is better, and rock
crystal is better than flint glass. A glass prism, however, will suit
our present purpose.
Casting by means of such a prism a spectrum, not upon the white
surface of our screen, but upon a sheet of paper which has been wetted
with a saturated solution of the sulphate of quinine and afterwards
dried, an obvious extension of the spectrum is revealed. We have, in
the first instance, a portion of the violet rendered whiter and more
brilliant; but, besides this, we have the gleaming of the colour
where, in the case of unprepared paper, nothing is seen. Other
substances produce a similar effect. A substance, for example,
recently discovered by President Morton, and named by him _Thallene_,
produces a very striking elongation of the spectrum, the new light
generated being of peculiar brilliancy.
Fluor spar, and some other substances, when raised to a temperature
still under redness, emit light. During the ages which have elapsed
since their formation, this capacity of shaking the ether into visual
tremors appears to have been enjoyed by these substances. Light has
been potential within them all this time; and, as well explained by
Draper, the heat, though not itself of visual intensity, can unlock
the molecules so as to enable them to exert their long-latent power of
vibration. This deportment of fluor spar determined Stokes in his
choice of a name for his great discovery: he called this rendering
visible of the ultra-violet rays _Fluorescence_.
Public-domain text, read in full here on John Shaqi.
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