Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
STANDARD THERMOMETER--The thermometer is graduated at zero and in tenth
degrees from 10deg. C. to 65deg. C., with one auxiliary reservoir at the
upper end and another between the zero mark and the 10deg. mark. The
cavity in the capillary tube between the zero mark and the 10deg. mark
is at least 1 cm. below the 10deg. mark, the 10deg. mark is about 3 or 4
cm. above the bulb, the length of the thermometer being about 37 cm.
over all. The thermometer has been annealed for 75 hrs. at 450deg. C.
and the bulb is of Jena normal 16''' glass, or its equivalent,
moderately thin, so that the thermometer will be quick-acting. The bulb
is about 3 cm. long and 6 mm. in diameter. The stem of the thermometer
is 6 mm. in diameter and made of the best thermometer tubing, with scale
etched on the stem, the graduation is clear-cut and distinct, but quite
fine. The thermometer must be certified by the U. S. Bureau of
Standards.
GLYCEROL CAUSTIC SOLUTION--Dissolve 250 g. potassium hydroxide in 1900
cc. dynamite glycerin with the aid of heat.
DETERMINATION--Heat 75 cc. of the glycerol-caustic solution to 150deg.
C. and add 50 g. of the melted fat. Stir the mixture well and continue
heating until the melt is homogeneous, at no time allowing the
temperature to exceed 150deg. C. Allow to cool somewhat and carefully
add 50 cc. 30 per cent sulfuric acid. Now add hot water and heat until
the fatty acids separate out perfectly clear. Draw off the acid water
and wash the fatty acids with hot water until free from mineral acid,
then filter and heat to 130deg. C. as rapidly as possible while
stirring. Transfer the fatty acids, when cooled somewhat, to a 1-in. by
4-in. titer tube, placed in a 16-oz. salt-mouth bottle of clear glass,
fitted with a cork that is perforated so as to hold the tube rigidly
when in position. Suspend the titer thermometer so that it can be used
as a stirrer and stir the fatty acids slowly (about 100 revolutions per
minute) until the mercury remains stationary for 30 seconds. Allow the
thermometer to hang quietly with the bulb in the center of the tube and
report the highest point to which the mercury rises as the titer of the
fatty acids. The titer should be made at about 20deg. C. for all fats
having a titer above 30deg. C. and at 10deg. C. below the titer for all
other fats. Any convenient means may be used for obtaining a temperature
of 10deg. below the titer of the various fats. The committee recommends
first of all a chill room for this purpose; second, an artificially
chilled small chamber with glass window; third, immersion of the
salt-mouth bottle in water or other liquid of the desired temperature.
UNSAPONIFIABLE MATTER.
EXTRACTION CYLINDER--The cylinder shall be glass-stoppered, graduated at
40 cc., 80 cc. and 130 cc., and of the following dimensions: diameter
about 1-3/8 in., height about 12 in.
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