Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
Soap is used to a very large extent in silk mills, both for degumming
the raw silk and in silk dyeing. Raw silk consists of the true silk
fibre known as fibroin and a gummy coating, sericin, which dulls the
lustre of the silk unless removed. For this purpose a slightly alkaline
olive oil foots soap is best adapted, although palm oil and peanut oil
soaps are sometimes used, as well as soaps made from a combination of
house grease to the extent of 30 per cent., together with red oil or
straight olein soaps, both of which are artificially colored green. In
using house grease, if 30 per cent. is exceeded in combination with red
oil, the titer is raised to such an extent that the soap does not
readily rinse from the silk nor dissolve readily. They are also not
advisable because they impart a disagreeable odor to the silk.
To make a soap for this purpose from olive oil foots it is made as a
settled soap, care being taken to thoroughly boil the mass on the
saponification change in the closed state to assure proper
saponification. The kettle is usually grained with lye and given a good
wash change to remove the excess strength. The change previous to the
finish should not be too heavy or too large a nigre results. The lighter
the grain is, the better the finished kettle is. A yield of 150 per
cent. is usually obtained. This soap is generally run to a frame,
slabbed upon cooling and packed directly into wooden cases.
For silk dyeing the above soap is suitable, although any well-made soap
of good odor and not rancid is useable. While soap alone is often used
in the bath for silk dyeing, certain dyestuffs require the addition of
acetic or sulphuric acid, which sets free the fatty acids. If these be
of bad odor it is taken up by the silk and is difficult to remove. The
most generally used soaps are the just mentioned olive foots soap or a
soap made from a good grade red oil.
Both kinds are extensively used.
SOAPS USED FOR COTTON GOODS.
In the manufacture of cotton goods, as compared to the wool and silk
industries, very much less soap is used and it is only applied to the
finished fabric either to clean the cloth preparatory to dyeing or to
aid in dyeing with certain colors. It is also used in calico printing.
For cleansing the cloth ordinary chip soap is suitable although a more
alkaline soap finished as a curd soap is an advantage in that the free
alkali contained therein aids in removing the dirt and has no harmful
effect on the cotton. For dyeing cotton goods or to brighten certain
colors after dyeing an olive oil foots soap is most generally employed.
In calico printing soap is used to wash and clear the cloth after
printing. A soap for this purpose should be easily soluble in water and
contain no free alkali, rosin or filler. The best soaps for use in
calico printing are either an olive oil foots soap or an olein soap.
SULPHONATED OILS.
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