_Exchange of bases in Zeolites._—Although zeolites rarely form a large proportion of rock-masses and therefore do not enter directly into the soil minerals to any great extent, their interest in connection with soil-formation is very great, because of the continuation, within the soil, of the same processes that bring about their formation in rocks. Under the conditions existing in soils they will naturally rarely form crystals, but will appear in the pulverulent or gelatinous form, leaving the zeolitic nature of the material to be inferred from its chemical behavior. Among these characters the ready decomposability by acids has already been mentioned; another of special importance in the economy of soils is the fact that when a pulverized zeolite is subjected to the action of a solution containing either of the stronger bases usually present (potash, soda or lime), such base or bases will be partially or wholly taken up by the zeolitic powder, while corresponding amounts of the bases originally present will pass into solution. Thus when a hydrosilicate of soda and alumina is digested with a solution of potassic chlorid or sulphate, the soda may be partially or wholly replaced by potash, while the corresponding sodium salt passes into solution. In the case of zeolites containing lime or magnesia or both, the action of potassic or sodic chlorid will be to partially replace the lime, while calcic and magnesic chlorids pass into solution, resulting in the partial or complete replacement of the lime by one or the other, or by both bases. It is important to note that, other things being equal, potash is usually absorbed in greater amounts and is held more tenaciously than soda. The process may frequently be partially or wholly reversed again, by subsequent treatment with large amounts of solutions of the displaced base or bases. Thus while a solution of potassic chlorid may be made to expel almost completely the sodium present in analcite, subsequent treatment with sodic chlorid solution will again almost completely displace the potash before taken up. The same happens when the natural mineral potash leucite, (see p. 32) of frequent occurrence in certain lavas, is pulverized and treated with a sodic solution; resulting finally in the production of a mass corresponding to natural analcite, the sodium mineral corresponding to leucite. In other words, in any zeolitic powder the alkaline or alkaline earth bases present may be partially or wholly displaced by digestion with an excess of solution of any of these, varying according to the amount of solution employed, and the length of time and temperature of action.