White mustard seed contains from 25 per cent. to 35 per cent. of an
inodorous fixed oil with a little tendency to become rancid and of
little pungency, which it will not give up in water. In place of
myronic acid converted into volatile oil of mustard, it contains a
non-volatile, bitter and acrid salt termed sulphocyanide of sinapine
(C_{17}H_{24}N_{2}SO_{5} or C_{16}H_{23}NO_{5}CNHS), myrosin gum
cellulose and mineral matter. Now, as it is on the volatile oil and
the acrid and somewhat bitter salt that the pungency and acridity of
mustard depend, we can see a strong reason why in the mustard of
commerce the farina of the two species, black and white seed, should
be blended together, in the proportion of two parts of white to one of
black. The black seed does contain some of the acrid principle as well
as the volatile oil, as has been verified by the action of nitric
acid, caustic potash, and ferric chloride, on the alcoholic extract.
It is, therefore, the most valuable of the two seeds on account of the
little volatile oil in the yellow seed. The acrid principle of white
mustard appears to possess but little stability, although it has been
said to bear a temperature of 130 degrees C. We find that it is
readily affected by heat and that it is not safe to evaporate the
alcoholic solution containing it at a higher temperature than about 30
degrees C., for, if subjected to a much higher temperature, it quickly
loses its acridity and acquires a bitter, caramel-like taste.
The oil extracted by ether from the brown seed is of a bright and
beautiful emerald-green color, owing to the peculiar green principle
described as one of its constituents. So deep and remarkable is the
color of the oil that it would be easy by means of a graduated scale of
tints to determine with very tolerable certainty the percentage of brown
mustard contained in any sample of mixed mustard. Specific gravity,
1.017; boils at 148 degrees.
Myronate of potash decomposes under the influence of the nitrogenous
matter contained in brown mustard into volatile oil, glucose, and acid
sulphate of potash. The quantity of each of these products of
decomposition gives, therefore, by simple calculation, the quantity of
myronic acid; one hundred parts of this acid yield 23.85 parts of
volatile oil.
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