The oil from the root contains cinnamyl aldehyde, hydrocarbon and
ordinary camphor, and is lighter than water, both the oil of the bark
and of the leaves being heavier. Oil from cinnamon bark and shoots is
seldom exported. The oil is obtained in Ceylon by macerating the
powdered bark or roots with a saturated solution of common salt for two
days, after which the whole is distilled.
Cinnamyl aldehyde, which is a very pleasant smelling colorless liquid,
may be separated from hydrocarbon, which is also found in the oil, by
bringing the oil in contact with concentrated nitric acid. The crystals,
which separate in long rhombic prisms or small plates, are decomposed by
water into nitric acid. Free cinnamyl aldehyde may be prepared by
allowing a mixture of ten parts benzolaldehyde, fifteen parts
acetaldehyde, 900 parts of water, and ten parts of a 10 per cent.
solution of caustic soda to stand eight or ten days, at a temperature of
30 degrees, the whole being frequently agitated. Finally the aldehyde is
extracted by means of ether.
The pure Chinese cassia lignea bark, essential oil 1.5 per cent., has a
specific gravity of about 1.035 to 1.060; aldehyde, 89.9 per cent., and
at 15 C. should have a specific gravity of 1.050 to 1.070. On
distilling, about 90 per cent. of pure cassia oil should pass over, and
the balance, 10 per cent. residue, must not become solid in cooling,
must not be brittle but must be in a semifluid state. If the oil
contains less than 70 per cent. of cinnamyl aldehydes it may be
considered adulterated, and at 75 per cent. should be handled with
suspicion.
14 to 9 years old, 79 per cent. Cinnamyl aldehyde
15 years old, 70 per cent. Cinnamyl aldehyde
16 years old, 73 per cent. Cinnamyl aldehyde
Cinnamic acid occurs in the flowers of cinnamon and forms in small
quantities by oxidation of the cinnamyl aldehyde when it comes in
contact with the open air. It will dissolve in 3,500 parts of water at
17 degrees and is more readily soluble in boiling water and crystallizes
from it in lustrous plates. From the cassia buds, refuse bark, young
shoots and roots a fragrant volatile substance is obtained which floats
on water, and when removed and allowed to cool, it becomes a suet,
giving a delicious odor in burning, called a cinnamon suet, or wax,
which is used largely by the Catholics and Buddhists in worship and at
high native weddings. It was formerly used in Ceylon for making candles.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account