Steam, Its Generation and UseBabcock & Wilcox Company
History
Steam, Its Generation and Use
Babcock & Wilcox Company
Steam-boilers, Water-tube
The weight of flue gases resulting from the combustion of a pound of dry
coal will be the sum of the weights of the air per pound of coal and the
combustible per pound of coal, the latter being equal to one minus the
percentage of ash as found in the boiler test. The weight of flue gases
per pound of dry fuel may, however, be computed directly from the
analyses, as shown later, and the direct computation is that ordinarily
used.
The ratio of the air actually supplied per pound of fuel to that
theoretically required to burn it is:
N
3.036(---------)×C
CO_{2}+CO
------------------ (13)
C O
34.56(- + H - -)
3 8
in which the letters have the same significance as in formulae (11) and
(12).
The ratio of the air supplied per pound of combustible to the amount
theoretically required is:
N
------------------ (14)
N - 3.782(O - ½CO)
which is derived as follows:
The N in the flue gas is the content of nitrogen in the whole amount of
air supplied. The oxygen in the flue gas is that contained in the air
supplied and which was not utilized in combustion. This oxygen was
accompanied by 3.782 times its volume of nitrogen. The total amount of
excess oxygen in the flue gases is (O - ½CO); hence N - 3.782(O - ½CO)
represents the nitrogen content in the air actually required for
combustion and N ÷ (N - 3.782[O - ½CO]) is the ratio of the air supplied
to that required. This ratio minus one will be the proportion of excess
air.
The heat lost in the flue gases is L = 0.24 W (T - t) (15)
Where L = B. t. u. lost per pound of fuel,
W = weight of flue gases in pounds per pound of dry coal,
T = temperature of flue gases,
t = temperature of atmosphere,
0.24 = specific heat of the flue gases.
The weight of flue gases, W, per pound of carbon can be computed
directly from the flue gas analysis from the formula:
11 CO_{2} + 8 O + 7 (CO + N)
---------------------------- (16)
3 (CO_{2} + CO)
where CO_{2}, O, CO, and N are the percentages by volume as determined
by the flue gas analysis of carbon dioxide, oxygen, carbon monoxide and
nitrogen.
The weight of flue gas per pound of dry coal will be the weight
determined by this formula multiplied by the percentage of carbon in the
coal from an ultimate analysis.
[Graph: Temperature of Escaping Gases--Deg. Fahr.
against Heat carried away by Chimney Gases--In B.t.u.
per pound of Carbon burned.[31]
Fig. 20. Loss Due to Heat Carried Away by Chimney Gases for Varying
Percentages of Carbon Dioxide. Based on Boiler Room Temperature = 80
Degrees Fahrenheit. Nitrogen in Flue Gas = 80.5 Per Cent. Carbon
Monoxide in Flue Gas = 0. Per Cent]
Fig. 20 represents graphically the loss due to heat carried away by dry
chimney gases for varying percentages of CO_{2}, and different
temperatures of exit gases.
Public-domain text, read in full here on John Shaqi.
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