Steam, Its Generation and UseBabcock & Wilcox Company
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Steam, Its Generation and Use
Babcock & Wilcox Company
Steam-boilers, Water-tube
Anthracite is the nearest approach to the ideal coal for storing. It is
not subject to spontaneous ignition, and for this reason is unlimited in
the amount that may be stored in one pile. With bituminous coals,
however, the case is different. Most bituminous coals will ignite if
placed in large enough piles and all suffer more or less from
disintegration. Coal producers only store such coals as are least liable
to ignite, and which will stand rehandling for shipment.
The changes which take place in stored coal are of two kinds: 1st, the
oxidization of the inorganic matter such as pyrites; and 2nd, the direct
oxidization of the organic matter of the actual coal.
The first change will result in an increased volume of the coal, and
sometimes in an increased weight, and a marked disintegration. The
changes due to direct oxidization of the coal substances usually cannot
be detected by the eye, but as they involve the oxidization of the
carbon and available hydrogen and the absorption of the oxygen by
unsaturated hydrocarbons, they are the chief cause of the weathering
losses in heat value. Numerous experiments have led to the conclusion
that this is also the cause for spontaneous combustion.
Experiments to show loss in calorific heat values due to weathering
indicate that such loss may be as high as 10 per cent when the coal is
stored in the air, and 8.75 per cent when stored under water. It would
appear that the higher the volatile content of the coal, the greater
will be the loss in calorific value and the more subject to spontaneous
ignition.
Some experiments made by Messrs. S. W. Parr and W. F. Wheeler, published
in 1909 by the Experiment Station of the University of Illinois,
indicate that coals of the nature found in Illinois and neighboring
states are not affected seriously during storage from the standpoint of
weight and heating value, the latter loss averaging about 3½ per cent
for the first year of storage. They found that the losses due to
disintegration and to spontaneous ignition were of greater importance.
Their conclusions agree with those deduced from the other experiments,
viz., that the storing of a larger size coal than that which is to be
used, will overcome to a certain extent the objection to disintegration,
and that the larger sizes, besides being advantageous in respect to
disintegration, are less liable to spontaneous ignition. Storage under
water will, of course, entirely prevent any fire loss and, to a great
extent, will stop disintegration and reduce the calorific losses to a
minimum.
To minimize the danger of spontaneous ignition in storing coal, the
piles should be thoroughly ventilated.
Public-domain text, read in full here on John Shaqi.
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