A familiar early experiment in electrolysis is the decomposition of
water--a chemical composed of oxygen and hydrogen, though always thought
of and used as a simple, pure fluid. If the poles of a galvanic battery
are immersed in water slightly mixed with sulphuric acid to favor
electrical action, these poles will become covered with bubbles of gas
which presently rise to the surface and pass off. These bubbles are
composed of the two constituents of water, the oxygen rising from the
positive and the hydrogen from the negative pole. Particles of the
substance decomposed are transferred, some to one pole and some to the
other; and, therefore, electrolysis is always practiced in a fluid in
order that this transference may more readily occur.
The quantity of _electrolyte_--the substance decomposed--that is
transferred in a given time is in proportion to the strength of the
current. When this electrolyte is composed of many substances a current
will act a little on all of them, and the quantity in which the
elementary bodies appear at the poles of the current depends upon the
quantities of the compounds in the liquid, and on the relative ease with
which they yield to the electrical action.
The electrolytic processes are not the mere experiments a brief
description of them would indicate, but are among the important
processes for the mechanical products of modern times. The extensive
nickel-plating that became a permanent fad in this country on the
discovery of a special process some years ago, is all done by
electrolysis. The silver plating of modern tableware and table cutlery,
as beautiful and much less expensive than silver, and the fine finish of
the beautiful bronze hardware now used in house-furnishing, are the
results of the same process. Some use for it enters into almost every
piece of fine machinery, and into the beautifying or preserving of
innumerable small articles that are made and used in unlimited quantity.
The process and its principle is general, but there are many details
observed in the actual work of electroplating which interest only those
engaged. One of the most usual of these is that of making an
electrotype. This may mean the making of an exact impression of a medal,
coin, or other figure, or a depositing of a coating of the same on any
metallic surface. Formerly the faces of the types used in printing were
very commonly faced with copper to give them finish and a wearing
quality. Even fresh, natural fruits that have been evenly coated with
plumbago may be covered with a thin shell of metal. A silver head may be
placed on the wood of a walking stick, precisely conforming on the
outside to the form of the wood within.
Public-domain text, read in full here on John Shaqi.
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