Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
According to United States Patent No. 1,800,295, dated April 14, 1931, a
resin fast to light and soluble in oils is obtained by heating 82 parts
of p-tertiary amyl phenol with 90 parts of formaldehyde, in the presence
of sodium hydroxide. This substituted phenol resin passes slowly into the
infusible state, thus permitting better control of the reaction.
Para tertiary butyl phenol.
Para tertiary butyl phenol is a white solid with an aromatic odor,
melting at approximately 100° C. It is a new commercial product and is
used in resins for paints and varnishes. It is the most important resin
material in this group.
Phenyl phenols.
Both ortho and para phenyl phenol are commercially produced and are used
to some extent in resins to replace phenol. The ortho isomer is a white
solid boiling at 284° C. and melting at about 56° C. It is used chiefly
as a germicide, though small quantities are used in resins.
Para phenyl phenol is a white solid melting at about 165° C. and boiling
at 322° C. Commercial production was reported for the first time in
1933. The output has increased each year since and the selling price has
gradually declined.
Resorcinol.
Resorcinol, usually obtained by fusing meta benzene disulphonic acid with
caustic soda, is a colorless, crystalline substance with a peculiar odor.
It melts at 119° C. and boils at 276° C. It is used in medicine, in the
manufacture of intermediates and dyes, and to some extent in synthetic
resins. Resorcinol condenses with formaldehyde at such a rapid rate
that some means must be applied to slow up the reaction. It is used to
increase the rate of condensation of tar-acid resins and to reduce the
danger of sticking or undercure.
Domestic production of resorcinol has decreased in recent years. Its
relatively high cost is probably an important factor in limiting its use
in synthetic resins.
FORMALDEHYDE
Description and uses.
At ordinary temperature and pressure formaldehyde is a gas. It enters
commerce as formalin, an aqueous solution containing 40 percent
formaldehyde by volume (37 percent by weight) and from 6 to 14 percent
methyl alcohol. It is generally made by the oxidation of methyl alcohol.
Commercial formalin contains polymers which tend to precipitate in water
solution; these are kept in solution by allowing from 6 to 14 percent
methyl alcohol to remain in the solution.
The principal use of formaldehyde is in the manufacture of synthetic
resins. Other uses are (in the order of their importance): In the
manufacture of synthetic indigo; in the manufacture of hydrosulphite; as
a disinfectant, deodorant, and preservative; as a fungicide; in embalming
fluids; in tanning leather; and in the manufacture of coated paper and
wallpaper.
United States production.
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