Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
Alvars are made by replacing part or all of the acetate groups in
Gelva with acetaldehyde. Their viscosity varies with the degree of
polymerization and their properties vary according to the extent of
replacement of the acetate groups. The Alvar types do not cold flow
when molded, are tougher, harder, and have better adhesion but are less
resistant to weathering than the Gelva types. Other properties are about
the same as those of the Gelvas. Alvars having 70 to 80 percent acetate
group replacement are used chiefly in spirit type varnishes, lacquers,
and enamels that must stand exposure to weather. Another Alvar type
is used in injection and press molding. The high binding power of the
resin permits the use of large percentages of filler without loss of
desirable properties. Such moldings may be machined and polished, and
take inserts, such as the wood core in shoe heels. Flexible phonograph
and transcription records made from the Alvars have gained wide approval.
An 85 percent (acetate replacement) type has better impact strength and
is used in toilet articles. Sheets, rods, and tubes of this resin may be
machined in much the same way as nitrocellulose plastic and used where
noninflammability is an asset.
Formvars are made by replacing part or all of the acetate groups in Gelva
with formaldehyde. These resins are colorless, odorless, tasteless, and
thermoplastic. They have higher softening points and greater tensile and
impact strength than the Alvars. They are resistant to alcohols, coal-tar
solvents, fats, oils, or water. Moisture transmission rate through a film
of this resin is about one-tenth that through regenerated cellulose and
one-fourth that through cellulose acetate.
The grades of the Formvars available are designated by the extent of
replacement of the acetate group. The 75-percent replacement type has
excellent mechanical strength and flexibility and is unaffected by
sunlight. Formvars of 95 percent acetate displacement have a tensile
strength as high as 10,000 pounds per square inch and offer possibilities
in the manufacture of artificial silk and photographic film.
The vinyl resins have made possible a new type of safety glass superior
to any heretofore marketed. By condensing butylaldehyde with vinyl
acetate, a polymer is obtained which is used as the inner layer between
two sheets of glass. Heat and pressure secure complete adhesion and yield
a sheet with greater resistance to breakage at low temperatures than the
types now in general use.
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