Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.United States Tariff Commission
Science
Synthetic resins and their raw materials: A survey of the types and uses of synthetic resins, the organization of the industry, and the trade in resins and raw materials, with particular references to factors essential to tariff consideration. Under the general provisions of section 332, title III, part II, Tariff act of 1930.
United States Tariff Commission
Gums and resins industry; Plastics
In lacquers the Vinylites offer high resistance to water, oils, and
chemicals. The drying of such lacquers is by evaporation rather than
by oxidation. They are suitable for lining food containers, coating
concrete, coating paper for bottle cap liners, and as a stiffener for
box toes of shoes. Their most successful application at present is as an
inside coating for beer cans. Floor tile containing these resins mixed
with slate flour or other filler has good possibilities.
_Polyvinyl chloride resins._—Vinyl chloride may be polymerized to give
nonflammable resins of varying solubilities. The completely polymerized
resin is practically insoluble at ordinary temperatures and is used as a
rubber substitute. It is marketed as Koroseal by B. F. Goodrich Rubber
Co., Akron, O. Compared with natural rubber, it has greater resistance to
acids, alkalies, oils, and alcohol, more flexing life, better resistance
to sunlight, water, and oxidation. Solutions of this resin marketed as
Korolac are used in special types of varnishes.
_Polyvinyl chloroacetate resins._—These resins known as Mowiliths are
made in Germany. Application is largely for surface coating. Practically
no information on this type is available.
_Divinyl acetylene and synthetic rubber._—Two products closely related
to those described above but probably not synthetic resins as defined
for this discussion are divinyl acetylene, a synthetic drying oil, and
Neoprene, a synthetic rubber.
Acetylene, when passed into a solution of copper chloride and ammonium
chloride, combines with itself. When two molecules of acetylene react
monovinyl acetylene is formed, and when three molecules of acetylene
react divinyl acetylene is formed. Monovinyl acetylene reacts with
hydrochloric acid to give chloroprene, which is polymerized to synthetic
rubber or Neoprene.
Divinyl acetylene is a colorless liquid which darkens on exposure to
light and which has an onionlike odor. When polymerized liquids are
formed, then as the reaction progresses viscous products and finally
insoluble, infusible, inert resins. By arresting the reaction before the
gel point is reached, an amber colored heavy liquid, soluble in aromatic
hydrocarbons, is obtained. Since divinyl acetylene will continue to
polymerize at ordinary temperatures, this property is taken advantage of
in using it as a basis for paints, under the name “synthetic drying oil.”
Clear, amber films are obtained from solutions of this oil in solvent
naphtha. Divinyl acetylene is quick drying, is many times more impervious
to moisture than linseed oil, and is thermosetting. It is not attacked
by solvents but is attacked by strong oxidizing agents, and the gelled
material may ignite spontaneously.
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