Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Gelatine-----------------Precipitate.
Ferric chloride----------Brown-black coloration.
Lead acetate-------------White precipitate, insoluble in
HNO_3.
Aniline hydrochloride----Slight precipitate.
Tanning experiments with this partly neutralised product resulted in a
very gradual conversion of the pelt into a greenish-grey coloured
leather; the colour, however, does not penetrate the pelt and is hence
caused by colloidally suspended impurities. If the solution is filtered
through a filter candle, a somewhat clearer solution results, but the
latter also tans very slowly and yields a brown coloured leather.
Analysis of the partly neutralised product reveals a tannin content of
17.6 per cent. A 2° Bé. solution of the non-neutralised product showed a
rapid tanning effect at first, when brought into contact with pelt, on
which it had a strong swelling effect, and to which it imparted a
greenish colour; the tanning effect, however, slowed down considerably,
after a few days, and the solution penetrated the pelt only very
gradually; this is probably due to the presence of large quantities of
colloidally suspended impurities, which, when the substance is partly
neutralised with the formation of salts of the sulphonic acids, are
brought into true solution and hence penetrate the pelt with greater
rapidity.
INDEX OF AUTHORS
Adler
Appelius
Ashmore
Bader
Badische Anilin u.(German abbreviation for "und") Soda-Fabrik
Baekeland
Baeyer
Berzelius
Biginelli
Boehringer & Sons
Bottinger
Braconnot
Buff
Caro
Chem. Fabrik Jucker & Co.
Chevreul
Dekker
Deutsch-Koloniale Gerb u. Farbstoff Gesellschaft
Deyeux
Dizé
Drabble
Edner
Elberfelder Farbenfabriken
Fahrion
Feist
Fischer, E.
Freudenberg
Froda
Gerhardt
Gesellschaft f.(German abbreviation for "für") Chem. Industrie, Basle
Graebe
Graham
Grasser
Hatchett
Heinemann
Herzig
Herzog
Hönig
Iljin
Immerheiser
Jennings
Kahl
Kauschke
Klepl
König
Kostanecki
Krafft
Krauss
Kunzemüller
Lauffmann
Liebig
Lipp
Lloyd
Löwe
Manning
Mauthner
Meunier
Michael
Mielke
Mitscherlich
Nierenstein
Paessler
Paternò
Payne
Pelouze
Perkin
Proust
Rapoport
Raschig
Reinsch
Resch
Russanow
Sabanajew
Sander
Scheele
Schiff
Schmidt
Schorlemmer
Seel
Seyewetz
Sisley
Skey
Stiasny
Strauss
Thuau
Tschirch
Vogel
Walden
Webster
Weinschenk
Wohl
Zacharias
A
Alcohol figure
Algarobilla
Alizarin
Alizarin yellow, in paste
Alkalies, reaction of, to Neradol D
Alum-neradol tannage
Alum tannage
Aminobenzene
Aminophenol, _p_-
Aniline dyes
Anthracene
Anthraquinone
Arylsulphaminoarylsulphonic acids
Arylsulphoxyarylsulpho acids
B
Bakelite
Bakelite solution
Benzoylamino 6-chloranthraquinone
Benzylsulphanilate sodium
Bismuth salts
Bleaching method for leather with Neradol D
Bloom
Bromo-[Greek: b]-naphthol
Bromonitrophenol
Bromophloroglucinol
Bromosalicylic acid
Bromotrinitrophenol
C
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