Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Of aromatic acids all those which yield water-soluble sulphonation
products seem suitable for the industrial production of tanning
matters. If the acids themselves do not yield water-soluble sulphonation
products, the alkali salts of the latter may be condensed with
formaldehyde, and the resulting products then constitute tanning matters
provided their solutions can be neutralised or faintly acidified without
the solute being thrown out of solution in insoluble form.
The diphenyl derivatives of the above groups often possess tannoid
properties.
The same holds good of those compounds with condensed nuclei
(naphthalene, anthracene, etc.), and all their derivatives which satisfy
the above conditions.
The choice of condensing agent is, as a rule, of little
significance. Elimination of the elements of water by the mere
application of heat succeeds in few cases only, since the high
temperature required to induce reaction in many cases causes
decomposition of the substances. This difficulty is overcome by heating
_in vacuo_. Condensation with formaldehyde always succeeds, with
acetaldehyde and benzaldehyde only partly.
The action on hide powder, pelt, and gelatine by these characteristic
substances is tabulated below:--
Relative Behaviour towards
Substance. Gelatine. Hide Powder Pelt
Formaldehyde ... ... Tanning
Phenol Ppte. ... ...
Chlorophenol " ... ...
Surface
Tribromophenol Slight ppte Tanning tanning
_o_ Nitrophenol No ppte " "
Bromonitrophenol Slight ppte " "
Trinitrophenol Ppte " Tanning
Bromotrinitrophenol Slight ppte " "
_p_ Aminophenol Ppte ... ...
_m_ Dihydroxybenzene " ... ...
Orcinol " ... ...
_p_ Dihydroxybenzene " Tanning Tanning
Monochloro _p_
dihydroxybenzene " ... ...
_o_ Dihydroxybenzene " ... ...
Pyrogallic acid " ... ...
Surface
Tribromopyrogallic acid " Tanning Tanning
Gallic acid No ppte Not tanning Not tanning
Bromophloroglucinol Ppte Tanning "
Gallotannic acid " " Tanning
Galloflavine Slight ppte " Not tanning
Quinone " " Tanning
Bromosalicylic acid " " Not tanning
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