Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Dinaphthylmethanedisulphonic acid Ppte " Tanning
Diphenylmethanedisulphonic acid " " "
Dicresylmethanedisulphonic acid " " "
Sodium
dicresylmethanedisulphonate acid No ppte " Not tanning
Dixylylmethanedisulphonic acid Ppte " Tanning
Naphtholdisulphonic acid " Not tanning Not tanning
Methylenedinaphthol " Tanning Tanning
Hydroxyphenylmethanesulphonic " " "
acid Not tanning
Hydroxynaphthylmethanesulphonic Slight ppte " "
acid
Diaminonaphthylmethanedisulphonic Ppte Tanning Not tanning
acid
Dihydroxynaphthylmethanedisulphonic
acid " " "
Dichloronaphthylmethanedisulphonic
acid " " Surface tanning
Dinitronaphthylmethanedisulphonic
acid " " "
Dithionaphthylmethanedisulphonic
acid " " Tanning
Bromo _[Greek: b]_ naphthol [1] Slight ppte " "
Rosolic acid_ [1] Ppte " "
[Footnote 1: In alcoholic solution.]
SECTION III
TANNING EFFECTS OF MIXTURES AND NATURAL PRODUCTS
1. Mixture of Phenolsulphonic Acid and Formaldehyde
The most important invention relatively to the search for new tanning
materials was that of Weinschenk,[Footnote: Ger. Pat., 184,449.] who
first showed that pelt may be converted into leather by the action upon
it of mixtures of naphthols and formaldehyde. This process consists of
two steps: the pelt is first immersed in a 0.25-0.50 per cent,
formaldehyde solution, and secondly in an aqueous solution of -[Greek:
a] or -[Greek: b] naphthol; this order may be reversed. If, on the other
hand, a pasty mixture is made of formaldehyde and naphthol, and this is
allowed to act upon the pelt, the latter is rapidly converted into
leather, but the mixture must be administered very gradually or
otherwise the insoluble methylenedinaphthol is formed outside the pelt
and hinders any tanning effect.
Leather obtained through the action of [Greek: a]-naphthol is, when
freshly tanned, pure white and sufficiently soft and firm, but quickly
assumes a brown colour on storing; if, however, [Greek: b]-naphthol is
employed, a cream-coloured leather results, the colour of which turns
only slightly more yellowish even when exposed to the direct rays of the
sun.
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