Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
These experiments prove that when pelt is treated with formaldehyde,
phenolsulphonic acid, and vegetable tannins, the two former components
effect, more or less, actual tannage; it is admittedly a matter of some
difficulty to establish whether the effect is one of pickling or
pseudo-tannage, or whether the tannage may be considered a true one. The
final effect, however, is nearly always that of a true tannage, _i.e_.,
by varying the composition of the tanning solutions leather is obtained
with properties identical with those tanned with true tannins of
vegetable origin. The only difficulty encountered in these combinations
is the property of formaldehyde, of precipitating the natural tannins,
and it is hence essential, for practical purposes, to so arrange the
combination that their value is not reduced by the property referred to.
The fact that not only compounds already existing may convert pelt into
leather, but that a similar effect is obtained _inside the pelt_, by
their components, is indeed of theoretical interest.
3. Tanning Effects of Different Natural Substances
In addition to the vegetable tannins, Nature has also provided other
substances of vegetable origin, which, admittedly, do not effect tannage
in their original state, but which may, by suitable treatment, acquire
this property. The oldest information on this point is supplied by
Resch, [Footnote: _Scherer's Jour_., 1801, 6, 495.] who carried out
tanning experiments, using three parts of peat and one part of oak bark.
By the action of nitric acid on substances of vegetable and animal
origin, Hatchett, [Footnote: _Gehlen's Jour_., 1805, 1, 545.] Chevreul,
[Footnote: _Ann. Chim_., 1810, 73, 36.] and Vogel [Footnote:
_Jour. Chem. Phys_., 1812, 6, 101.] claim to have obtained tanning
materials, whilst later, Buff [Footnote: _Ibid_., 1827, 51, 38.]
obtained a material suitable for tanning purposes from indigo.
By subsequent treatment with lime and soot, or tar, Ashmore [Footnote:
_Dingier's Jour_., 1833, 48, 67.] claims to have converted pelt into
leather.
By treating peat with nitric acid, Jennings [Footnote:
_Jahresber. d. Chem_., 1858, 666.] and Payne [Footnote: _
Chem. Centralbl_., 1908, ii. 554; Ger. Pat., 200, 539.] have produced
artificial tanning materials.
Skey [Footnote: _Chem. News_, 1866, 206; _Zeits. f. Chem_., 1866, 753.]
obtained a dark brown extract, soluble in water and precipitating
gelatine, by treating bituminous coal or lignite with nitric acid; by
extracting coal with alkalies, Reinsch [Footnote: _Pharm. Centralh_.,
1887, 141.] isolated a substance (pyrofuscine) which, when partly
neutralised with carbon dioxide, was capable of converting pelt into
leather.
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