Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Sixty grammes of phenolsulphonic acid were partly neutralised with 100
c.c. of a 10 per cent solution of caustic soda, and 10 c.c. formaldehyde
added to 400 c.c. of the mixture (2º Bé.): a piece of pelt was
completely penetrated by the solution in sixteen hours, and was
subsequently tanned in two days, using an extract of 10º Bé. Similarly,
by treating a pelt with 400 c.c. of a half-neutralised solution of
phenolsulphonic acid (3º Bé.) plus 8 c.c. formaldehyde, and adding after
eighteen hours sulphited quebracho extract to the same bath,
strengthening the latter to 6º Bé., the pelt was converted into leather
in two days; in this case, however, much of the tannin was precipitated
by the formaldehyde present in the solution. If, on the other hand, a
mixture of 80 gm. dilute phenolsulphonic acid (1:1 aq) and 14 gm. of
formaldehyde were cooled for several hours and subsequently strengthened
with sulphited quebracho extract to 7º Bé., no tannin was precipitated
in the liquor, and a piece of pelt immersed in the latter was completely
tanned in sixteen hours.
To prevent the precipitation of tannin caused by the formaldehyde,
sulphite cellulose extract (wood pulp) was substituted for sulphited
quebracho extract, and the following experiments carried out:--
To 200 c.c. of a 6º Bé. sulphite cellulose extract plus 200 c.c. of
half-neutralised phenolsulphonic acid solution was added 15
c.c. formaldehyde, and this solution tanned pelt in four days; the
resultant leather was light brown, firm, and possessed good tensile
strength and long fibre.
Another piece of pelt was immersed in a solution of 400
c.c. phenolsulphonic acid of 3ºBé. plus 15 c.c. formaldehyde for
eighteen hours, and was then tanned in a 6º Bé. solution of sulphite
cellulose extract. The resultant leather was extremely light coloured,
and possessed qualities similar to those described in the former
experiment. Finally, pelt was immersed in a 6° Bé. solution composed of
140 gm. of a 15° Bé. sulphite cellulose extract, 10 gm. of formaldehyde,
400 gm. water, 15 gm. phenolsulphonic acid, and 30 gm. of a 10 per cent
caustic soda solution, and was tanned in four days. This leather also
was coloured light brown, of good tensile strength, and rather firm.
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