Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Whereas the evaluation of vegetable tanning matters necessitates
determinations of their practical applicability in addition to
qualitative and quantitative analyses, the latter two determinations are
of practically no value when dealing with synthetic tannins. The way in
which tanning matters obtained by chemical means exert their action, in
addition to the intensity with which they convert pelt into leather, is
the only criterion of their quality for practical (tanning) purposes;
both may be demonstrated by experimental tests.
When dealing with the natural tanning materials it is desirable to know
their contents of actual tanning matter, from which their special
qualities as tanning agents may be deduced. Where the vegetable tanning
materials have already been converted into extracts, it is essential to
establish the identity of the original material used by the qualitative
reactions of the extract in addition to the quantitative estimation of
actual tannin contents. It is frequently necessary to examine whether
the extract in question has been actually prepared from the material
giving the extract its name, or whether the extract has suffered the
addition of other extracts of tanning materials of but low quality. Such
determinations may be undertaken by microscopical observations and by
means of qualitative and quantitative reactions; for this purpose many
colour reactions and precipitation methods are available in addition to
the determination of the molybdenum figure (Lauffmann),[Footnote:
Collegium, 1913, 10.] the alcohol and ethyl acetate figures and
microscopical examination (Grasser).[Footnote: Ibid., 1911, 349.] Of
other adulterants tending to reduce the quality of extracts may be
mentioned sugars, mineral salts, and coal-tar dyes; [Footnote: Grasser,
_Collegium_, 1910, 379.] for the determination of these, the special
literature should be consulted. [Footnote: Grasser, "Handbuch
f. gerbereichem. Laboratorien" (Leipzig, 1914);
Procter-Paessler, "Gerbereichem. Untersuchungen" (Berlin, 1901).]
Two methods are devised for the purpose of quantitatively determining
the tannin contents, both of which employ hide powder, and which are
known as the "shake method" and the "filter bell method" respectively:
the former is adopted as the official method of the "International
Association of Leather Trades' Chemists" (I.A.L.T.C.). [Footnote: And
also by the Society of Leather Trades' Chemists.-_Transl._]
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