Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
The original method, [Footnote: _Leather Manufacturer_, 1894, No. 9
J.S.C.I.,1894, 494.] worked out in the laboratory of the Yorkshire
College (now the University of Leeds), essentially consists in
introducing 6-9 gm. of hide powder in a shaker, washing it at least
twice with distilled water and carefully squeezing out the powder in a
linen cloth between each washing. 100 c.c. of the solution to be
examined, which may not contain more than 1 per cent, total solids, are
introduced into the shaking bottle which is then weighed. About
one-third of the washed hide powder is then added, and the bottle shaken
ten to fifteen minutes; another third is then added and, after shaking,
the third portion. The bottle plus contents is now weighed, and the
amount of hide powder introduced ascertained by difference of the two
weighings. The liquid is then filtered through filter paper, 50 c.c. of
the clear filtrate evaporated in a basin, dried and weighed. The residue
in the original solution is then obtained by multiplying the former by
100 (plus weight of water added with hide powder), and dividing by 100.
This method was closely investigated by a large number of leather
trades' chemists, was considerably improved, and in its final form
presented a method of the highest degree of accuracy; the method was
therefore adopted as _The Official Method of Tanning Analysis_ by the
I.A.L.T.C., which body, at the same time, gave precise instructions as
to the details of the method. The latest instructions, which are
reprinted below, permit of any method of analysis which observes the
following conditions:--
1. The solution for analysis must contain between 3.5 and 4.5 gm. of
tanning matter per litre, and solid materials must be extracted so that
the greater part of the tannin is removed at a temperature not exceeding
50° C.
2. The total solubles must be determined by the evaporation of a
measured quantity of the solution previously filtered till optically
clear, both by reflected and transmitted light. This is obtained when a
bright object such as an electric light filament is distinctly visible
through at least 5 cm thickness, and a layer of 1 cm. deep in a beaker
placed on a black glass or black glazed paper appears dark and free from
opalescence when viewed from above. Any necessary mode of filtration may
be employed, but if such filtration causes appreciable loss when applied
to a clear solution, a correction must be determined and applied as
described in paragraph 6.
Filtration shall take place between the temperatures of 15° C. and 20°
C. Evaporation to dryness shall take place between 98.5° C. and 100°
C. in shallow, flat-bottomed basins, which shall afterwards be dried
until constant at the same temperature, and cooled before weighing for
not less than twenty minutes in air-tight desiccators over dry calcium
chloride.
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