Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
Comparative tanning tests using products containing sulphuric acid and
products free from sulphuric acid (neutralised to the same degree of
acidity) yielded leathers which were very similar; the liquor containing
no sulphates yielded slightly softer leather than that obtained from a
liquor containing sulphates.
An experiment was also carried out, using a liquor containing the tannin
completely neutralised with caustic soda and subsequently acidified with
acetic acid till the acidity of 1 gm. = 10 c.c N/10 NaOH; here, again,
no essential difference could be detected in the leather as compared
with that from a liquor containing sulphates.
One of the most striking properties of this tanning matter is its
solubilising effect on natural tannins and the phlobaphenes; this
property may mainly be compared to the similar one of other condensed
sulphonic acids in their behaviour towards natural tannins.
If, therefore, natural tannins are mixed with this product and the
solution used for tanning purposes, the resultant leather will possess a
dark colour owing to the presence of solubilised phlobaphenes; if, on
the other hand, a dark coloured leather, which has been tanned with
natural tannins, is washed over with a 5° Bé solution of this synthetic
tannin, or immersed for some time in the solution, the leather assumes a
lighter colour owing to the phlobaphenes being dissolved and removed
from the leather by the synthetic tannin.
The presence of Neradol ND in leathers is detected by methods to be
described under Neradol D (_cf_. p. 108). The oxyazo reaction only
succeeds when the solution has been boiled with a few drops of
hypochlorite solution, quickly cooled and excess of ammonia added. When
applying the indophenol reaction, the solution must be treated as
follows: 3-4 drops of hypochlorite solution is added, and the solution
heated for a short time; or 5-6 drops hypochlorite solution may be
added, and the solution left for some time, in which case the heating
may be omitted. The solution is then made distinctly ammoniacal, 1-2
drops of dimethyl-_p_-phenylenediamine solution and a layer of alcohol
poured on the top. In most cases a blue coloration will appear; the
addition of 1-2 drops of potassium ferricyanide solution with formation
of a blue coloration indicates the presence of Neradol ND without fail.
The fact that a product possessing tanning properties may be obtained by
condensing [Greek: b]-naphthalenesulphonic acid makes it interesting to
investigate the behaviour of a non-condensed [Greek:
b]-naphthalenesulphonic acid towards pelt. The following solutions were
allowed to act upon pelt for twelve days:--
(1) Concentrated solution of [Greek: a]-naphthalenesulphonic acid (10° Bé).
(2) " " [Greek: b]- " " (6° Be.)
(3) " " 2,7- " " (18° Bé.).
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