Synthetic Tannins, Their Synthesis, Industrial Production and ApplicationGrasser, Georg
Science
Synthetic Tannins, Their Synthesis, Industrial Production and Application
Grasser, Georg
Tannins
If concentrated phenolsulphonic acid is gradually neutralised with
concentrated caustic soda solution till the former is faintly alkaline,
the sodium salt thus obtained is not so easily condensed with
formaldehyde as is the case with the free acid.
1. If formaldehyde is gradually added to the neutralised phenolsulphonic
acid in the cold, opalescence immediately results; on addition of water,
the liquid assumes a milky appearance. On adding gelatine to this
liquid, a slimy precipitate is thrown down, leaving a slightly
opalescent liquid.
2. If formaldehyde is added to neutralised phenolsulphonic acid whilst
it is heated on the water bath, a slimy mass instantly separates, which
on cooling solidifies and forms a greyish-blue brittle mass, insoluble
in water and but sparingly soluble in alcohol; the alcoholic solution is
capable of converting pelt into leather.
The filtrate from the solidified mass strongly precipitates gelatine,
whereas the insoluble condensation product is soluble in caustic soda;
this alkaline solution also precipitates gelatine and the addition of
acetic acid transforms the mixture into the gel state.
If the insoluble condensation product is dissolved in warm concentrated
sulphuric acid, the solution remains clear upon the addition of water,
but does not precipitate gelatine. If, finally, this solution is
neutralised with caustic soda, the solution remains clear and
precipitates gelatine strongly.
D. Condensation of Cresolsulphonic Acid
Experiments were carried out with the object of condensing _o_-, _m_-,
and _p_-cresolsulphonic acids with formaldehyde in various ways; no
essential differences could be detected as regards the mode of reaction
or the properties of the intermediary and end-products as compared to
those of phenolsulphonic acid. Similarly, condensation of different
samples of crude cresol containing varying quantities of _o_-, _m_-, and
_p_-cresol did not yield end-products sufficiently different to justify
describing them in detail.
E. Relative Behaviour of an Alkaline Solution of Bakelite and Natural
Tannins
Phenolsulphonic acid was condensed with a little formaldehyde, and the
reddish pasty condensation product dissolved in caustic soda. This
alkaline solution of bakelite was exactly neutralised with acetic acid
and mixed with strong solutions of an untreated quebracho extract. It
was observed that the solubility of the quebracho extract was not
increased by this treatment, but the faintly acidic character of the
natural tannin caused the bakelite to be thrown down as an insoluble
precipitate.
Crude phenolsulphonic acid, when added to a solution of the quebracho
extract referred to, does not increase the solubility of the latter,
which even deposits considerable amounts of insoluble tannin particles.
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