Chemically an examination of the ash of tea-leaves also affords some
criteria which may also be utilized for the purpose of identifying the
true tea-leaf. For instance, in common kinds of wood, such as oak, deal
and pine, the proportion of ash is a few-tenths per cent. of the whole,
and by taking wood in its ordinary air-dried condition it contains some
20 to 30 per cent. of moisture. Leaves, on the other hand, contain 10,
20 and even 30 times as much mineral matter, there being doubtless a
connection between this abundance of mineral matter and the active
chemical changes which take place in the leaves during the growth of the
plant. In tea-leaves, therefore, as in leaves in general, the ash
amounts to a considerable percentage, usually averaging about 6 per
cent., so that a chemical examination of the ash forms an important part
of the analysis of tea. The proportion of ash in all teas is tolerably
constant, genuine tea rarely yielding so little as 5 and never exceeding
6 per cent. of ash on incineration. Therefore, to determine the amount
of ash, weigh a small quantity of the tea in its ordinary commercial
state and burn it in a platinum crucible and then re-weigh the resultant
ash; by observing a few simple precautions very constant and accurate
results are attainable by this method. The crucible should be clean and
bright, the lid fitting precisely; an iron triangle, covered with a
tobacco pipe may be employed to support the crucible during ignition.
The operation is then commenced by igniting the empty crucible, and
allowing it to cool, being placed for that purpose on a piece of
porcelain or iron, immediately weighing the crucible on becoming cold.
Next place one or two grams of tea in the crucible, weighing both
together, and ignite over a spirit lamp or good gas-burner, stirring the
contents with a platinum wire for a few minutes. When ignition is
complete the crucible is covered with the lid, let cool again and
immediately weighed a second time. If there is any doubt as to the
completeness of the ignition, the crucible must be again ignited, and if
there is no difference in weight, the ignition is thereby proved
finished. As is obvious, in order to obtain accurate results it is
indispensable that the crucible should be in the same condition when it
is weighed empty and when weighed with the ash, and this is insured by
the preliminary ignition and rapid re-weighing, as above described.
The following determinations of the percentages of ash in spurious
leaves most used in the adulteration of tea, dried after the manner of
tea, may serve to illustrate, the leaves being gathered towards the end
of August:—
Kind of Leaf. Per cent. of Ash.
Ash, 9.40
Plum, 9.90
Willow, 9.34
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