Is frequently introduced into tea with the object of adding weight, and
is best detected by the “ash-test.” As formerly stated, the leaves of
genuine tea, or tea of fair commercial value, yield from 5 to 6 per
cent. of ash or mineral matter on incineration, 2 per cent. of which is
again soluble in water. This rate is fairly constant, and ranges from 5
in Black teas to 6 per cent. in pure Green, rarely yielding as low as 5
in the former and never exceeding 6 in the latter, while many of the
teas of commerce are found to yield from 13 to 20 per cent. of ash on
incineration. Such teas are unmistakably sophisticated, and will be
found, on analysis, to contain sand or other mineral matter in their
composition.
To determine the amount of mineral matter contained in teas so
adulterated, proceed as in the case of spurious and spent leaves, which
analysis may be again confirmed by a determination of the ratio of
soluble to insoluble matter contained in the ash. The result is obtained
by boiling the ash in a little water and filtering the precipitate,
drying, burning, weighing and subtracting the residue or insoluble
matter from the original weight of the ash. By this process both the
soluble and insoluble parts are ascertained, and if the sample be pure,
but 3 to 3½ per cent. of insoluble will remain, any increase of these
figures clearly denoting adulteration to that extent.
Where the burning of the leaves is inconvenient, the following operation
may be substituted: Weigh a sample of the suspected tea and boil with
about ten times its weight of water in a porcelain dish or beaker. This
boiling will wash the sand off the leaves and sink to the bottom, the
leaves floating in the liquid. When the liquid has cooled sufficiently,
the leaves may be removed with the hand, the liquid and sand being
poured into a filter. The sand is then washed, dried and ignited in a
platinum plate and weighed, in which manner the amount of sand yielded
by 50 or 100 grams of tea may be actually weighed and ascertained. On
examining the analysis it will be found that tea-ash contains a quantity
of iron and some manganese, the presence of the latter being so marked
in tea-ash, that on subsequent treatment of the ash with water a deep
green solution of the manganate is obtained. Owing to the presence of
this chemical, tea-ash also evolves chlorine very perceptibly,
particularly when treated with hydrochloric acid. If the sample of tea
treated yield _only_ the normal percentage of ash at the same time
contains a considerable quantity of silica, such a combination would
afford the strongest evidence of adulteration. This will be apparent
from the fact that tea-ash is an essential part of the tea, and if a
part of the tea-ash be absent, the sample must have been deprived of at
least the corresponding quantity of tea. Spent leaves contain less ash
than genuine tea, the average being about 3.06 of ash in 100 parts of
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