In the Spiller mine, about 15 miles northeast of Mason in Mason County, masses of braunite occur as lens-shaped layers in Precambrian gneiss and quartzite rocks. This braunite may have formed from another manganese mineral (possibly manganese garnet) that was exposed at the earth’s surface after the overlying rocks eroded away. As this other mineral weathered, it may have altered into braunite, or the braunite could have been deposited from solutions emanating from hot magmas before the great thickness of overlying rock was removed. The mineral variety _hollandite_ is a rare manganate of manganese and barium. It has a metallic luster, and its color is silvery gray or black. When you rub it across a streak plate, hollandite leaves a black streak. It has a specific gravity of 4.7 to 5. Hollandite is rather hard, but a steel file will scratch it. [Illustration: Hollandite from Jeff Davis County, Texas.] Hollandite occurs in western Jeff Davis County in west Texas at what is called the Mayfield prospect. Here, it is found as rounded masses that occur in a vein near a large fault in Lower Cretaceous limestone rocks. Other manganese compounds, _pyrolusite_ and _wad_, are found in several important deposits near the Pecos River in western Val Verde County. _Pyrolusite_ is a manganese dioxide mineral. It is black, opaque, and so soft that it rubs off on your fingers like soot. Pyrolusite may be granular and massive or may be powdery. It also occurs as a fern-like coating on rocks. _Wad_ is not really a mineral but is an impure, dull-black or brownish-black mixture of manganese oxide, water, and other substances. It can be soft enough to soil your fingers, or it can be too hard to scratch with a pocket knife. Wad occurs in earthy or compact masses or in crusts or stains on rocks. In Val Verde County, the wad and pyrolusite are found mixed with soil, clay, gravel, sand, and plant remains. This material fills cracks in Lower Cretaceous limestones, it is scattered through gravels, and it is deposited in low places at the surface. The manganese in these deposits came from limestone rocks that have since weathered away. Rainwater trickled into these rocks and dissolved the manganese minerals they contained. This manganese was washed down toward the Pecos River and was deposited as wad and pyrolusite. Marble Marble is a metamorphic rock made up chiefly of sparkling grains of calcite or dolomite, but other minerals may be present. The marble may be fine grained, medium grained, or coarse grained; commonly, all the mineral grains are about the same size.