Sulfur does not conduct electricity and is a poor conductor of heat. You
can test how poorly heat passes through it by holding a fragment of
sulfur up to your ear. You may be able to hear a crackling sound. The
sound results when the outer part of the fragment expands (due to the
heat from your hand) while the inner part (which has received no heat)
remains unchanged.
Crystals of sulfur are sometimes found, and most of them have either a
double-pyramid shape or a flat, tabular shape. Sulfur also occurs as
compact masses, as crusts, and as scattered grains.
Native sulfur deposits are found in two widely separated areas of
Texas—one in west Texas and the other along the Gulf Coast in southeast
Texas, extending over into Louisiana. In the Gulf Coast area, native
sulfur is found on some of the salt domes.
The salt domes are huge (from about half a mile to more than 2 miles
across), column-shaped masses made up of halite and some anhydrite.
These masses have pushed up toward the surface through thousands of feet
of sand, clay, and other sedimentary rocks. On top of many of the salt
columns is a covering of limestone (calcite), anhydrite, and gypsum
known as the _cap-rock_. It is in this cap-rock that the sulfur is
found.
It is thought that when the masses of halite and anhydrite pushed toward
the earth’s surface, some of the upper part of the halite dissolved. The
anhydrite, however, did not dissolve, and it remained on top of the salt
column. Then, a part of this anhydrite was altered into the gypsum,
limestone, and sulfur that now are found in some of the cap-rocks.
Laboratory experiments have shown that the sulfur in the cap-rocks
likely formed through the action of sulfate-reducing bacteria. These
bacteria, in the presence of petroleum, converted the sulfate in some of
the anhydrite into hydrogen sulfide. Later, hydrogen sulfide was
oxidized—perhaps by reaction with more of the anhydrite—to form the
sulfur.
Most of the large cap-rock sulfur deposits are about 1,500 to 2,400 feet
underground. At first, an attempt was made to get this sulfur out of the
ground by digging shafts down to it, but loose, wet, caving sands and
poisonous gases, such as hydrogen sulfide, made this mining method
almost impossible. Finally, a chemist, Herman Frasch, found a way to
obtain the sulfur by making use of sulfur’s low melting point. When
sulfur gets slightly hotter than boiling water (235° to 247°
Fahrenheit), it melts and becomes a dark, yellowish-brown liquid.
Public-domain text, read in full here on John Shaqi.
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