Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
There is often some clue as to the nature of the poison afforded, and
the investigation should be made for it first; the presence or absence
of other poisons, however, must be determined. If there be no clue,
then a systematic examination must be carried out. The poison must be
looked for not only in the contents of the stomach, but in the viscera
as well; it must be remembered that poison may be introduced into the
stomach after death.
Volatile poisons, such as alcohol, chloroform, prussic acid, may be
separated by distillation after acidulation with tartaric acid. Arsenic
is best separated by drying the organic material, and distilling after
adding strong hydrochloric acid.
Other metallic poisons may be tested for, with or without destruction
of organic matter. To destroy the organic matter, the _moist method_
is the one in general use: After reducing the contents of the stomach
or the viscus to a pulp, they are mixed with distilled water to the
consistency of thin gruel, and placed in a flask with some crystals
of potassium chlorate--half an ounce to each pound of the liquid.
Pure hydrochloric acid is added, and the flask gently heated on a
water bath, a mixture of chlorine and oxides of chlorine is given off
and gradually breaks up the organic matter, converting at the same
time any mineral poison present into the chloride. This procedure is
followed until the material becomes quite limpid, more chlorate or
hydrochloric acid may be added if necessary. It is then transferred to
an evaporating dish and heated on the water bath until the smell of
chlorine disappears. It is then filtered while hot, to allow chloride
if present to pass through; a stream of sulphur dioxide is passed
through the filtrate when cold, to reduce any metals present to a lower
state of oxidation. Silver chloride will not pass through the filter in
this process, so it has to be dealt with in a special manner.
In making a systematic analysis, volatile poisons must be tested for
first, then ascertain the presence or absence of alkaloids, after which
the inorganic poisons must be dealt with.
CHAPTER II
DIVISION I.--CHEMICAL
CORROSIVE POISONS
THE MINERAL ACIDS
_General Characters._--The mineral acids have no remote effects on the
system; their action is purely local. They are seldom used for the
purpose of homicide, except in the case of young children. By suicides
they are more frequently employed.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account