Text-book of forensic medicine and toxicologyBuchanan, R. J. M. (Robert James McLean)
Science
Text-book of forensic medicine and toxicology
Buchanan, R. J. M. (Robert James McLean)
Medical jurisprudence; Poisons
The _post-mortem_ appearances are inflammation and softening of the
mucous membrane of the mouth, gullet, and stomach, which may also be
covered with chocolate-coloured or black spots. When life has been
prolonged for some months the stomach may become contracted, the
pyloric orifice scarcely admitting the passage of a fine probe.
_Chemical Analysis._--The caustic alkalies are known from their
carbonates by giving a brown precipitate with nitrate of silver;
whereas their carbonates give a white, and also effervesce on the
addition of an acid.
The following table will show the reaction of these alkalies with
reagents:
To distinguish Caustic Potash from Caustic Soda
+--------------------+--------------------------+-----------------+
| | Potash. | Soda. |
+--------------------+--------------------------+-----------------+
| Bichloride of | A canary-coloured | No precipitate. |
| platinum. | precipitate | |
| | in solutions | |
| | acidulated with | |
| | hydrochloric acid. | |
| | | |
| Strong solution of | Precipitate in granular | No precipitate. |
| tartaric acid. | white crystals. | |
| | | |
| Colour given to | Rose or lilac tint. | Yellow tint. |
| flame. | | |
| | | |
| Neutralised with | Crystallises in long, | Crystallises in |
| nitric acid. | slender, fluted prisms.| rhombic plates.|
+--------------------+--------------------------+-----------------+
_In Organic Mixtures._--If the mixture be strongly alkaline, filter and
test as above.
_Fatal Period._--From three hours to as many years.
_Fatal Dose._--About half an ounce of the caustic alkali. The smallest
fatal dose recorded of caustic potash is forty grains.
_Treatment._--Water freely; drinks containing citric or acetic acid,
vinegar, lemon juice, oil, linseed tea, and other demulcent drinks. The
stomach tube should be avoided.
AMMONIA
In vapour, in solution, or solid.
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